极低成本的燃料电池氧还原催化剂替代品

Rajapakse Rmg, Senarathna Kgc, A. Kondo, Jayawardena Ps, M. Shimomura
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引用次数: 5

摘要

燃料电池为当今有用的能源危机提供了一种可行的替代能源技术。然而,燃料电池为汽车提供动力的主要障碍之一是在两种半反应中使用的催化剂的巨大成本,这两种半反应分别是Pt和Pt- rh,分别用于阳极和阴极半反应。在降低燃料电池成本的几种策略中,降低铂的使用量和用低成本的催化剂替代昂贵的铂是实现燃料电池动力汽车发展的两种主要途径。我们已经率先开发了这种低成本的催化剂,用于困难的半反应,即燃料电池的氧还原半反应。本文介绍了用于燃料电池氧还原半反应的银/聚吡啶/蒙脱土催化剂的研制及其活性,该催化剂的性能与昂贵的Pt-Rh催化剂相当。我们发现这种催化剂的功能与昂贵的Pt-Rh催化剂非常相似,因此在实际应用中前者可以方便地取代后者。
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Extremely Low-Cost Alternative for the Oxygen Reduction Catalyst of FuelCell
Fuel cells offer an enabling alternative energy technology for the present day useful energy crisis. However, one of the major obstacles of fuel cells in powering motor vehicles is the enormous cost associated with the catalysts used in both half-reactions which are Pt and Pt-Rh, respectively, for the anodic and cathodic half-reactions. Among several strategies put forward to reduce the cost of fuel cells, lowering of the amount of platinum used and replacing highly expensive platinum by low-cost catalysts are two major approaches to realize the development of fuel cellpowered motor vehicles. We have been pioneered in developing such low-cost catalysts for the difficult half-reaction, viz., the oxygen reduction half reaction of the fuel cells. We present here the development and the activity of Ag/ Polypyrrole/Montmorillonite Clay catalyst which performs equally to expensive Pt-Rh catalyst used for the oxygen reduction half-reaction of fuel cells. We show that this catalyst functions very similar to highly expensive Pt-Rh catalyst and hence the former can be conveniently substituted for the latter in practical applications.
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