贵金属的MO CVD

I. Igumenov
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引用次数: 20

摘要

综述了化学气相沉积贵金属(Pt、Pd、Rh、Ir、Ru、Au)涂层的研究和应用现状。系统的已知实验数据的合成,热性能和饱和蒸汽压的贵金属挥发性化合物与有机配体提供。从一般要求到前驱体,分析了贵金属气相沉积的工艺。结果表明,螯合或混合配体贵金属配合物,特别是β-二酮酸衍生物,由于其热学性质是最适合贵金属厚膜的沉积。
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MO CVD of Noble Metals
The state of the art in research and application of processes of chemical vapour deposition of noble metal (Pt, Pd, Rh, Ir , Ru, Au) coatings is considered. Systematization of known experimental data on synthesis, thermal properties and saturated vapour pressure of volatile compounds of noble metals with organic ligands is provided. The processes of CVD of noble metals were analized from general requirements to precursors. It is shown that chelate or mixed-ligand noble metal complexes and, in particular β-diketonate derivatives due to their thermal properties are the most suitable for deposition of noble metal thick films.
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