有机铝化合物的电化学

I. Shterenberg, Michael Salama, Y. Gofer, D. Aurbach
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引用次数: 0

摘要

在本章中,介绍了有机铝化合物电化学的选定和最重要的方面。它的重点是两个主要的实现:电化学镀铝和可充电镁电池。详细讨论了有机铝基电镀液的电化学性能,并说明了溶液配方对电化学性能的影响。介绍了有机铝化合物作为路易斯酸在可充电镁电池电解液配方中的作用及其对电解液性能的影响。关键词:铝;organoaluminum化合物;电沉积;离子液体;镁电池;无水的电化学
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Electrochemistry of Organoaluminum Compounds
In this chapter, selected and the most important aspects of the electrochemistry of organoaluminum compounds are described. It is focused on two main implementations: electrochemical aluminum plating and rechargeable Mg batteries. Electrochemical aspects of organoaluminum-based electroplating baths are discussed in detail and the effects of the solutions formulation on the electrochemical properties are explained. The role of organoaluminum compounds, acting as Lewis acids, in the formulation of the electrolyte solutions for rechargeable Mg batteries, and their effect on the performance of electrolyte solutions is described. Keywords: aluminum; organoaluminum compounds; electrodeposition; ionic liquids; magnesium batteries; non-aqueous electrochemistry
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