作为碳纳米结构可靠生物来源的木素:提取和表征

F. S, B. Deeraj, Gejo George, K. Joseph
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摘要

本文提出利用椰髓木质素作为一种廉价可靠的碳源制备生物基碳质材料。选择椰子髓是因为它储量丰富,且木质素含量高达38-59.5%。采用碱提法从椰子髓中提取木质素,得率为45%。然后,将提取的木质素经过不同的程序,将其转化为ID/IG比为0.35的碳纳米纤维和在没有活化剂的情况下具有1089.1 m2/g高表面积的碳填料。因此,制备的碳质填料是聚合物基体的潜在增强剂,因为这些填料可以为复合材料提供足够的机械和热稳定性。此外,由于其优异的电导率(0.221 S/cm),碳质纳米材料适合多功能复合材料的应用。据我们所知,这是第一个基于椰髓木质素作为碳前体的工作。
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Coir Pith Lignin as a reliable bio-source for Carbonaceous Nano-structures: Extraction and characterization
This paper signifies using coir pith lignin as a cheap and reliable carbon source for preparing bio-based carbonaceous material. The coir pith is selected as it is abundantly available and has a very high lignin content of 38-59.5%. The soda extraction process does the extraction of lignin from coir pith with a yield of 45%. This extracted lignin is then subjected to a different procedure to transform it into carbon nanofibers with an ID/IG ratio of 0.35 and carbon fillers with a high surface area of 1089.1 m2/g without the presence of an activating agent. Thus prepared carbonaceous fillers are potential reinforcements for polymer matrices as these fillers may provide sufficient mechanical and thermal stability to the composites. Furthermore, due to their excellent electrical conductivity, 0.221 S/cm, the carbonaceous nanomaterials are suitable for multifunctional composite applications. This is the first work based on coir pith lignin as a carbon precursor to the best of our knowledge.
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