基于NI - 3AL金属间化物的耐热合金钎焊填充金属的设计

V. Kvasnytskyi, V. Korzhyk, V. Kvasnytskyi, H. Mialnitsa, C. Dong, T. Pryadko, M. Matviienko, Ye.A. Buturlia
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引用次数: 5

摘要

在燃气轮机工程中最有前途的结构材料之一是基于金属间化物的合金,ni3al类型,具有等轴和定向柱状结构。这些材料可以将叶片的工作温度提高到1220°C。叶片采用真空精密铸造的方法制造;在这种情况下,有必要在技术上将喷嘴叶片连接成块,固定冷却叶片中的信号孔,纠正铸造缺陷。熔化金属间化合物材料以及其他铸造耐热镍合金(HNA)的焊接没有产生积极的结果。因此,使用各种钎焊技术,如tlp键合(瞬态液相键合)。填充金属的熔点比主金属的熔点低。如何提高钎焊接头的物理力学性能和使用性能是钎焊技术的关键问题,包括设计合适的钎料。本文报道了钎料的合理掺杂、钎料的抑制剂、钎料的临界温度和表面性能、钎料的化学成分、钎焊接头的结构和性能、模态参数以及钎焊工艺。为了提高钎焊接头的组织稳定性和高温强度,在钎料中加入铼和钽合金。在乌克兰进行了900°C下钎焊接头的力学试验;温度高达1100摄氏度——在中华人民共和国。结果表明,以Ni - 3al型金属间化物为基体的等轴结构合金化合物在1100℃时的短期强度为主金属强度的0.98;相同温度下的持久强度满足主金属强度要求
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Designing Brazing Filler Metal for Heat-Resistant Alloys Based on NI 3AL Intermetallide
One of the most promising structural materials in gas turbine engineering is the alloys based on an intermetallide, the type of Ni 3 Al, with an equiaxial and directional columnar structure. These materials make it possible to increase the working temperature of blades to 1,220 °C. The blades are made by the method of precise casting in a vacuum; in this case, it is necessary to technologically join the nozzle blades into blocks, to fix the signal holes in cooled blades, to correct casting defects. Welding by melting intermetallide materials, as well as other cast heat-resistant nickel alloys (HNA), does not yield positive results. Therefore, various brazing techniques are used such as TLP-Bonding (Transient Liquid Phase Bonding). Filler metals' melting point is lower than that of the main metal. The key issue related to the technology of brazing HNA, including the design of appropriate filler metals, is the improvement of the physical-mechanical and operational properties of brazed joints. This paper reports the established rational doping of a filler metal base, as well as depressants, the critical temperatures and surface properties of filler metals, their chemical composition, the structure and properties of brazed joints, the mode parameters, and brazing technology. To improve the stability of the structure and the high-temperature strength of the brazed joints, the filler metal was alloyed with rhenium and tantalum. Mechanical tests of brazed joints at 900 °C were conducted in Ukraine; at a temperature of 1,100 °C ‒ in the People's Republic of China. The test results showed that the short-term strength of alloy compounds with an equiaxial structure based on the Ni 3 Al-type intermetallide at 1,100 °C is 0.98 of the strength of the main metal. The long-lasting strength at the same temperature meets the requirements for the strength of the main metal
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