不锈钢在高温下的尿素腐蚀

Anastasiia Galakhova, Fabian Kadisch, G. Mori, Susanne Heyder, H. Wieser, B. Sartory, Simon Burger
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引用次数: 3

摘要

研究了尿素水溶液高温分解对不锈钢的腐蚀机理。采用红外光谱、扫描电镜和立体显微镜研究了尿素水溶液及其热分解产物与不锈钢腐蚀机理的关系。通过在钢板上注入尿素水溶液,在高温下得到腐蚀的钢样和沉积物。沉积层下的均匀腐蚀是钢样品腐蚀的主要驱动因素。在裂缝处,由于使用的几何形状和高温循环造成的腐蚀也可能起到加速作用。
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Corrosion of Stainless Steel by Urea at High Temperature
The corrosion mechanism of stainless steel caused by high temperature decomposition of aqueous urea solution has been investigated. The relationship between aqueous urea solution, its thermal decomposition products and the corrosion mechanism of stainless steel is studied by FTIR spectroscopy, SEM and stereo microscopy. The corroded steel samples, together with deposits, were obtained from the injection of aqueous urea solution on the steel plate at high temperatures. Uniform corrosion underneath the deposits was proposed as the main driver for corrosion of the steel samples. At the crevices, corrosion due to the used geometry and due to high temperature cycling could play an acceleration role as well.
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