Cs3CoCl5磁性中心的结构

S. Lukin, O. P. Teslya
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引用次数: 2

摘要

研究了四边形晶体Cs3CoCl5的力学变形对Co2+离子四面体中心EPR谱的影响。分离了基态零场分裂形成的两种主要机制(磁性配合物的体积和形状的改变)。顺磁离子四面体最近环境畸变角(γ - γ0 = - 0.8°)与x射线分析数据吻合较好。考虑了四面体磁中心畸变符号与零场参数D符号的相关性。[俄语文本忽略。]
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The Structure of the Magnetic Centre in Cs3CoCl5
The influence of mechanical deformation of the tetragonal crystal Cs3CoCl5, on the EPR spectrum of the Co2+ ion tetrahedral centres is studied. The contributions of two main mechanisms of forming of ground state zero-field splitting (modifications of volume and “shape” of the magnetic complex) are separated. The calculated angle of the distortion of tetrahedral nearest environment of the paramagnetic ion (γ – γ0 = −0.8°) is in good agreement with the X-ray analysis data. The correlation of sign of the tetrahedral magnetic centre distortion with the sign of the zero-field parameter D is considered. [Russian text ignore.]
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