{"title":"芳烃对角鲨烷氧化稳定性的影响(二)","authors":"S. Yasutomi, T. Sakurai","doi":"10.1627/JPI1959.19.21","DOIUrl":null,"url":null,"abstract":"The co-oxidation of model compounds of aromatic hydrocarbon with squalane was carried out to investigate the effect of aromatic hydrocarbons on the oxidation stability of squalane. The kinetic parameters for the co-oxidation of some combinations with squalane were determined. The reactivity of squalane peroxy radical is nearly the same as that of cumyl peroxy radical, whereas the estimated value of 2kt for squalane peroxy radical is considerably larger than that for simple tertiary peroxy radicals. From this result, it should be considered that so-called \"Optimum Aromaticity\" could never occur in the co-oxidation with squalane. Actually, the effect of \"Optimum Aromaticity\" does not occur at all in the present work as expected.","PeriodicalId":9596,"journal":{"name":"Bulletin of The Japan Petroleum Institute","volume":null,"pages":null},"PeriodicalIF":0.0000,"publicationDate":"1977-05-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"The Effect of Aromatic Hydrocarbons on the Oxidation Stability of Squalane (Part 2)\",\"authors\":\"S. Yasutomi, T. Sakurai\",\"doi\":\"10.1627/JPI1959.19.21\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"The co-oxidation of model compounds of aromatic hydrocarbon with squalane was carried out to investigate the effect of aromatic hydrocarbons on the oxidation stability of squalane. The kinetic parameters for the co-oxidation of some combinations with squalane were determined. The reactivity of squalane peroxy radical is nearly the same as that of cumyl peroxy radical, whereas the estimated value of 2kt for squalane peroxy radical is considerably larger than that for simple tertiary peroxy radicals. From this result, it should be considered that so-called \\\"Optimum Aromaticity\\\" could never occur in the co-oxidation with squalane. Actually, the effect of \\\"Optimum Aromaticity\\\" does not occur at all in the present work as expected.\",\"PeriodicalId\":9596,\"journal\":{\"name\":\"Bulletin of The Japan Petroleum Institute\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":0.0000,\"publicationDate\":\"1977-05-25\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Bulletin of The Japan Petroleum Institute\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1627/JPI1959.19.21\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Bulletin of The Japan Petroleum Institute","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1627/JPI1959.19.21","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
The Effect of Aromatic Hydrocarbons on the Oxidation Stability of Squalane (Part 2)
The co-oxidation of model compounds of aromatic hydrocarbon with squalane was carried out to investigate the effect of aromatic hydrocarbons on the oxidation stability of squalane. The kinetic parameters for the co-oxidation of some combinations with squalane were determined. The reactivity of squalane peroxy radical is nearly the same as that of cumyl peroxy radical, whereas the estimated value of 2kt for squalane peroxy radical is considerably larger than that for simple tertiary peroxy radicals. From this result, it should be considered that so-called "Optimum Aromaticity" could never occur in the co-oxidation with squalane. Actually, the effect of "Optimum Aromaticity" does not occur at all in the present work as expected.
京公网安备 11010802042870号
京ICP备2023020795号-1
分享
求助内容：
应助结果提醒方式：
扫码关注我们
