{"title":"氢原子与氢氧根离子发生反应,产生溶剂化电子","authors":"Martyn C.R. Symons, Donald N. Zimmerman","doi":"10.1016/0020-7055(76)90088-7","DOIUrl":null,"url":null,"abstract":"<div><p>Exposure of aqueous alkaline glasses to <sup>60</sup>Co <em>γ</em>-rays followed by photobleaching to remove e<sub>t</sub><sup>−</sup> resulted in E.S.R. spectra dominated by O<sub>t</sub><sup>-</sup> and H·<sub>t</sub><sup>-</sup>, but at <em>ca</em>. 110 K H·<sub>t</sub> was lost and e<sub>t</sub><sup>−</sup> reappeared.</p></div>","PeriodicalId":100688,"journal":{"name":"International Journal for Radiation Physics and Chemistry","volume":"8 3","pages":"Page 395"},"PeriodicalIF":0.0000,"publicationDate":"1976-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0020-7055(76)90088-7","citationCount":"2","resultStr":"{\"title\":\"Reaction of hydrogen atoms with hydroxide ions to give solvated electrons\",\"authors\":\"Martyn C.R. Symons, Donald N. Zimmerman\",\"doi\":\"10.1016/0020-7055(76)90088-7\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>Exposure of aqueous alkaline glasses to <sup>60</sup>Co <em>γ</em>-rays followed by photobleaching to remove e<sub>t</sub><sup>−</sup> resulted in E.S.R. spectra dominated by O<sub>t</sub><sup>-</sup> and H·<sub>t</sub><sup>-</sup>, but at <em>ca</em>. 110 K H·<sub>t</sub> was lost and e<sub>t</sub><sup>−</sup> reappeared.</p></div>\",\"PeriodicalId\":100688,\"journal\":{\"name\":\"International Journal for Radiation Physics and Chemistry\",\"volume\":\"8 3\",\"pages\":\"Page 395\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"1976-01-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://sci-hub-pdf.com/10.1016/0020-7055(76)90088-7\",\"citationCount\":\"2\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"International Journal for Radiation Physics and Chemistry\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/0020705576900887\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"International Journal for Radiation Physics and Chemistry","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/0020705576900887","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Reaction of hydrogen atoms with hydroxide ions to give solvated electrons
Exposure of aqueous alkaline glasses to 60Co γ-rays followed by photobleaching to remove et− resulted in E.S.R. spectra dominated by Ot- and H·t-, but at ca. 110 K H·t was lost and et− reappeared.