淀粉/聚乙烯醇(PVA)共混生物塑料:合成及其理化性能

B. Shrestha, K. Chapain, Sambridhi Shah, R. Pandit
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引用次数: 0

摘要

淀粉基生物塑料是从食品废料中制备的,是一种寿命短的生物降解塑料,广泛应用于家庭和食品包装。本文以马铃薯皮中提取的甘油增塑淀粉为原料,与不同组分(wt.-%)的聚乙烯醇(PVA)共混制备了生物塑料,并用傅里叶变换红外光谱(FTIR)对其进行了表征,并对其吸水性、生物降解性、耐酸碱性等理化性能进行了研究。淀粉基生物塑料与PVA共混后的FTIR光谱峰位于2924 cm-1处,表明淀粉基生物塑料与PVA具有良好的相容性。吸水试验表明,淀粉/聚乙烯醇共混物中淀粉比例的增加使其吸水能力增加。淀粉/聚乙烯醇共混生物塑料中淀粉质量比越高,降解速度越快。淀粉含量较高的生物塑料可分别耐酸碱45小时和42小时而不溶解。
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Starch/ Polyvinyl Alcohol (PVA) Blend Bioplastics: Synthesis and Physicochemical Properties
Starch-based bioplastics are prepared from the waste of food materials and are widely used as the short-lived biodegradable plastic for household and food packaging applications. In this work, glycerol plasticized starch (extracted from potato peels)bioplastics blended with Polyvinyl Alcohol (PVA) in various compositions (wt.-%) were prepared, and characterized using Fourier Transform Infrared (FTIR) spectroscopy and their physicochemical properties such as water absorption, biodegradable properties, and acid-base resistance were investigated. The FTIR spectra of starch-based bioplastics blended with PVA of the peak at 2924 cm-1 portrayed good compatibility between starch bioplastics and PVA. The water absorption test showed that the increase in starch proportion in starch/PVA blend increases water absorption capacity. The higher weight ratio of starch in starch/ PVA blend bioplastics degraded more rapidly than other bioplastics. Furthermore, the bioplastics of higher starch content resist acid and base for 45 and 42 hours respectively without being dissolved.
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