聚丙烯-石英高填充复合材料的物理力学和热变形性能

Zeynab A. Ganbarli, Hamida R. Azizbayli, Shafaq R. Bagirova
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引用次数: 0

摘要

研究了石英(二氧化硅)含量对聚丙烯基复合材料主要物理力学性能的影响。结果表明,在复合材料中加入相容剂——聚丙烯与马来酸酐的共聚物,可以改善混合组分的性能和相容性。研究了材料的极限拉应力、抗拉屈服强度、断裂伸长率、维卡软化温度和熔体流动指数等性能。使用合成聚乙烯蜡作为增塑剂,可以显著提高高填充复合材料的变形能力。石英的浓度在5.0 - 25% wt之间变化,增塑剂的浓度在1.0 - 3.0% wt之间变化。热力学研究的方法表明,在20-250℃的温度范围内,热力学曲线的变化规律取决于石英、增塑剂和硫化剂的浓度。所进行的复杂研究为增强复合材料和提高其维卡软化温度开辟了新的可能性。
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PHYSICAL-MECHANICAL AND THERMAL DEFORMATION PROPERTIES OF PLASTICIZED HIGHLY FILLED COMPOSITES BASED ON POLYPROPYLENE AND QUARTZ
The influence of quartz content (silicon dioxide) on the main physical-mechanical properties of composites based on polypropylene is considered. It is shown that the loading of a compatibilizer – a copolymer of polypropylene with maleic anhydride – into the composition of the composite improves the properties and compatibility of the mixed components of the mixture. Properties such as ultimate tensile stress, tensile yield strength, elongation at break, Vicat softening temperature and melt flow index were studied. The use of synthesized polyethylene wax as a plasticizer made it possible to significantly improve the deformability of highly filled composites. The quartz concentration was varied within 5.0–25 % wt., and the plasticizer concentration was 1.0–3.0 % wt. The method of thermomechanical studies shows the patterns of change in thermomechanical curves in the temperature range of 20–250 °C, depending on the concentration of quartz, plasticizer and vulcanizing agent. The complex of studies carried out has opened up new possibilities for strengthening composites and increasing their Vicat softening temperature.
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