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{"title":"汞氧化(II)","authors":"E. Leahy","doi":"10.1002/047084289X.RM038","DOIUrl":null,"url":null,"abstract":"[21908-53-2] HgO (MW 216.59) \n \n \n \n \n \nInChI = 1S/Hg.O \n \n \n \nInChIKey = UKWHYYKOEPRTIC-UHFFFAOYSA-N \n \n \n \n(promotion of thio-Claisen rearrangement;2 deprotection of dithianes, dithiolanes,3 thioorthoesters;4 synthesis of tetrahydrofurans;5 oxidizing agent6-18) \n \n \n \nAlternate Name: mercuric oxide. \n \n \n \nPhysical Data: mp 500 °C (dec); d 11.14 g cm−3. \n \n \n \nSolubility: sol dilute HCl, HNO3; insol water, ethanol. \n \n \n \nForm Supplied in: commercially available in both yellow and red crystalline forms. \n \n \n \nHandling, Storage, and Precautions: highly toxic; oxidizer; protect from light.","PeriodicalId":11669,"journal":{"name":"Encyclopedia of Reagents for Organic Synthesis","volume":"s3-10 1","pages":""},"PeriodicalIF":0.0000,"publicationDate":"2001-04-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Mercury(II) Oxide\",\"authors\":\"E. Leahy\",\"doi\":\"10.1002/047084289X.RM038\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"[21908-53-2] HgO (MW 216.59) \\n \\n \\n \\n \\n \\nInChI = 1S/Hg.O \\n \\n \\n \\nInChIKey = UKWHYYKOEPRTIC-UHFFFAOYSA-N \\n \\n \\n \\n(promotion of thio-Claisen rearrangement;2 deprotection of dithianes, dithiolanes,3 thioorthoesters;4 synthesis of tetrahydrofurans;5 oxidizing agent6-18) \\n \\n \\n \\nAlternate Name: mercuric oxide. \\n \\n \\n \\nPhysical Data: mp 500 °C (dec); d 11.14 g cm−3. \\n \\n \\n \\nSolubility: sol dilute HCl, HNO3; insol water, ethanol. \\n \\n \\n \\nForm Supplied in: commercially available in both yellow and red crystalline forms. \\n \\n \\n \\nHandling, Storage, and Precautions: highly toxic; oxidizer; protect from light.\",\"PeriodicalId\":11669,\"journal\":{\"name\":\"Encyclopedia of Reagents for Organic Synthesis\",\"volume\":\"s3-10 1\",\"pages\":\"\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2001-04-15\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Encyclopedia of Reagents for Organic Synthesis\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1002/047084289X.RM038\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Encyclopedia of Reagents for Organic Synthesis","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1002/047084289X.RM038","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
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