探索酸处理膨润土在各种催化应用中的潜力

D. Gandhi, Vatsal A. Pandya, Dr. Sachin Parikh
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摘要

粘土因其独特的层状结构和低廉的成本被广泛用作催化剂和催化剂载体。本文评价了印度古吉拉特邦膨润土作为催化剂的潜力。膨润土具有高阳离子交换能力、高吸附能力、粘性、可膨胀层等有利特性,可广泛应用于化工过程中的催化工业。用5 ~ 10M硫酸(H2SO4)处理膨润土,然后在600℃下煅烧,可以去除金属杂质,提高孔隙率。通过湿法工艺分析和红外光谱对改性粘土的理化特性进行了表征。结果表明,酸强度的提高可以更好地去除Al3+离子和其他金属氧化物,从而提高硅铝比。较好的表面特性表明,古吉拉特邦膨润土适合用作催化剂和催化剂载体。
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Exploring the Potential of Acid Treated Bentonite Clay for Various Catalytic Applications
Clays are widely used as catalysts and catalyst supports for a broad range of chemical processes due to their unique layered structure and low cost. Potential of Bentonite clay from Gujarat region (India) as a catalyst is evaluated in this work. Beneficial properties such as high cation exchange capacity, high absorption capacity, stickiness, expandable layer etc. makes Bentonite clay suitable for a wide range of catalytic applications in chemical process industries. Treatment of Bentonite clay with 5 - 10M sulphuric acid (H2SO4) followed by calcination at 600 0C showed removal of metallic impurities which increased porosity. The physical and chemical characteristics of modified clay were checked by WET process analysis and FTIR. Results showed that increase in acid strength led to better removal of Al3+ ion and other metal oxides thereby increasing silica-alumina ratio. Better surface characteristics indicate that Gujarat Bentonite clay is suitable for use as catalysts and catalyst supports.
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