海洋宏观褐藻Colpomenia sinuosa (Mertens ex Roth) Derbes and Solier纳米银的生物合成及表征

M. Kiran, S. Murugesan
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引用次数: 9

摘要

以海褐藻为原料,采用绿色合成方法合成了高效、经济、可扩展的银纳米颗粒。由于海洋宏观褐藻富含植物化学物质、生物活性化合物和次生代谢物,且具有环境可接受和生态友好的还原剂,因此本研究以其作为生物合成纳米银的实验材料。利用紫外可见光谱(UV-vis)和傅里叶红外光谱(FT-IR)对海洋宏观褐藻中生物合成的纳米银进行了表征,证实了纳米银的表面等离子体共振,并鉴定了生物分子中存在的各种官能团,这些官能团负责银离子的生物还原和纳米银的覆盖/稳定。通过x射线衍射(XRD)观察了纳米银的面心立方(fcc)和结晶性质,热重分析(TGA)揭示了纳米银的热稳定性和纯度。通过扫描电镜(SEM)研究了银纳米颗粒的粒径分布和形貌,发现银纳米颗粒的粒径范围在54 ~ 85 nm之间。利用透射电镜(TEM)分析了不同纳米尺度下的颗粒分布。
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Biosynthesis and Characterization of Silver Nanoparticles from Marine Macroscopic Brown Seaweed Colpomenia sinuosa (Mertens ex Roth) Derbes and Solier
In the present study energy efficient, economically scalable colloidal silver (Ag) nanoparticles were biosynthesized from marine brown seaweed Colpomenia sinuosa by green synthesis method. The marine macroscopic brown seaweed Colpomenia sinuosa was used in the experimental study for the biosynthesis of silver nanoparticle since they are rich in phytochemicals, bioactive compounds and secondary metabolites which has reducing agents that may be environmentally acceptable and eco-friendly. The biosynthesized silver nanoparticles from marine macroscopic brown seaweed were characterized by UV-vis spectroscopy which confirmed the surface plasmon resonance of silver nanoparticles, Fourier transform infrared (FT-IR) spectroscopy to identify the presence of various functional groups in biomolecules responsible for the bio reduction of Ag+ and capping/stabilization of silver nanoparticles. X-ray diffraction (XRD) to observe face center cubic (fcc) and crystalline nature of silver nanoparticles, thermogravimetric analysis (TGA) which revealed the thermal stability and purity of the silver nanoparticles. Particle size distribution and morphology were investigated by scanning electron microscope (SEM) which showed silver nanoparticles in the size range of 54-85 nm. The particle distribution under different nanometers was analyzed using transmission electron microscopy (TEM).
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