A. Babapoor, B. Mirzayi, Laleh Salehghadimi, Raha Hadi, S. Farhoudian, Meysam Paar
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引用次数: 0
摘要
本研究采用绿色简单水热法合成了一种新型的CoMnFeO4-MWCNT纳米复合材料,并通过FT-IR、x射线衍射、扫描电镜、EDX和高分辨率透射电镜分析对其结构进行了表征。选择循环伏安法和恒流充放电法作为策略来比较它们的超级电容器性能。在3mol L−1 KOH溶液中,当工作电压为1.2 V时,CoMnFeO4-MWCNT纳米复合材料的比电容约为1310 F g−1 (1a g−1)。此外,这种纳米复合材料在10000次充放电循环后仍保持89%的初始电容。此外,还进行了一些初步的机理研究,以更深入地了解纳米复合材料的电化学行为,这意味着CoMnFeO4-MWCNT纳米复合材料的氧化还原过程通常是准可逆的和扩散控制的。从时间、涂层和环境的角度来看,水热法更可靠、更有利、性能更高。
Novel CoMnFeO4-MWCNT nanocomposite based on a green synthesized method for supercapacitor applications
A novel nanocomposite of CoMnFeO4-MWCNT has been synthesized via green and simple hydrothermal method and the structure characterization has been done through FT-IR, X-ray diffraction, scanning electron microscopy, EDX, and high-resolution transmission electron microscopy analysis in this research. Cyclic voltammetry and galvanostatic charge–discharge methods are picked as the strategies to compare their supercapacitor behavior. The specific capacitance of about 1310 F g−1 (at 1 A g−1) in 3 mol L−1 KOH has been recorded for CoMnFeO4-MWCNT nanocomposite when the working voltage is 1.2 V. Moreover, this nanocomposite retains 89% of its initial capacitance after 10 000 charge–discharge cycles. Also, some initial mechanistic studies are performed to achieve a deeper insight into the electrochemical behavior of the nanocomposite implying that the oxidation-reduction process of CoMnFeO4-MWCNT nanocomposite is generally quasi-reversible and diffusion-controlled. From the view of time, coat, and environment, the hydrothermal process is much more reliable and beneficial regarding higher performance.
期刊介绍:
Published since 1929, the Canadian Journal of Chemistry reports current research findings in all branches of chemistry. It includes the traditional areas of analytical, inorganic, organic, and physical-theoretical chemistry and newer interdisciplinary areas such as materials science, spectroscopy, chemical physics, and biological, medicinal and environmental chemistry. Articles describing original research are welcomed.