天然裂缝性碳酸盐岩储层的先进Eor泡沫:泡沫和界面张力之间的最佳平衡

E. Chevallier, S. Bouquet, N. Gland, F. Douarche, G. Batôt
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引用次数: 5

摘要

在天然裂缝型碳酸盐岩储层中,油气重力泄油技术(GOGD)已经成功实施,但其采收率受到缓慢动力学的限制。然而,天然气EOR工艺是提高石油产量的一个有希望的替代方案。然而,该工艺的设计需要解决几个技术挑战:典型的不利的基质润湿性(中等至强油湿性),密集连接的裂缝网络以及裂缝-基质渗透率的高对比。我们在此建议注入具有降低界面张力的高级EOR泡沫。裂缝中的泡沫流产生了重要的粘性驱动,导致压力梯度,与GOGD相比,提高了采收率动态。此外,原油与水相之间的界面张力(IFT)降低,使得水相能够进入基体,尽管润湿性不利。在本文中,我们证明了IFT和泡沫强度性能之间存在平衡,以优化工艺。三种泡沫配方在IFT和泡沫性能方面进行了优化。对于他们的设计,优先考虑超低IFT值(10-3mN/m)或具有较大IFT (0.35mN/m)的强泡沫,或者在前两种配方之间取得平衡(0.03mN/m)。泡沫在超低IFT条件下本质上不太稳定:当IFT从10 - 3到10 - 1mN/m时,与油接触的表观粘度(在多孔介质中)分别提高了40倍。根据填砂和岩心驱油实验,我们推荐的IFT为10−1 mN/mas,以平衡裂缝中的粘性驱力和油湿基质中有效的水相渗吸。模拟工作支持了这一实验结论:SP驱中毛细管去饱和曲线确定的10−3 mN/m量级的IFT共同目标可以调整到更高的IFT值,这可以从储层的润湿性推断出来。为了确保在天然裂缝型碳酸盐岩油藏中加速采油,我们建议设计一种低IFT泡沫配方,与传统的针对剩余油的表面活性剂-聚合物工艺相比,该配方具有改进的IFT性能。事实上,如果IFT的目标是根据润湿性要求而不是剩余油的脱饱和度来定义,那么最终的过程可能会更有效。本文给出了目标配方参数,这些参数是由起作用的机理(油湿基质中的粘性驱动和渗吸)引起的,并且是用工业表面活性剂实际实现的。
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Advanced Eor Foam in Naturally Fractured Carbonates Reservoirs : Optimal Balance Between Foam and Interfacial Tension Properties
In naturally fractured carbonate reservoirs, Gas Oil Gravity Drainage processes (GOGD) are successfully implemented but oil recovery is limited by a slow kinetics. However a gas EOR process represents a promising alternative to boost this oil production rate. Nevertheless the design of this process should address several technical challenges: the typically unfavorable wettability of the matrix (intermediate to strongly oil-wet), the densely connected fracture network and the high contrast of fracture-to-matrix permeability. We propose here the injection of a advanced EOR foam with reduced interfacial tension. The foam flow in the fracture creates an important viscous drive leading to a pressure gradient, which increases the oil recovery dynamics compared to GOGD. Besides, the reduced interfacial tension (IFT) between crude oil and aqueous phase allows the aqueous phase to enter the matrix despite the unfavorable wettability. In this paper, we demonstrate that a balance exist between IFT and foam strength performances to optimize the process. Three foam formulations are optimized with very different profiles in terms of IFT and foam performances. For their design, priority is given either to ultra-low IFT values (10-3mN/m) or to a strong foam with larger IFT (0.35mN/m) or to a balance between the two first formulations (0.03mN/m). Foams are evidenced as intrinsically less stable in ultra-low IFT conditions: apparent viscosity (in porous media) in contact with oil is respectively enhanced by a factor 40 when IFT rises from 10−3 to 10−1mN/m. Based on sandpack and coreflood experiments, we recommend an IFT in the order of 10−1 mN/mas a balance between the viscous drive in fracture and an efficient aqueous phase imbibition in the oil-wet matrix. Simulation work supports this experimental conclusion: the common target of IFT in the order of 10−3 mN/m determined by capillary desaturation curves in SP flooding can be adjusted to a higher IFT value, which can be deduced from the wettability of the reservoir. To ensure an accelerated oil recovery in naturally fractured carbonate reservoirs, we recommend the design of a low-IFT foam formulation with revised IFT performances compared to a classical Surfactant-Polymer process targeting residual oil. Indeed, the final process is likely more efficient if the target of IFT is defined by wettability requirements rather than residual oil desaturation. This article gives the target formulation parameters which arise from the mechanisms at play (viscous drive and imbibition in oil-wet matrix), and are realistically achieved with industrial surfactants.
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