{"title":"高分辨率俄歇电子能谱研究了苯、环己烯和环己烷在清洁和碳化铁(110)表面上的化学吸附和分解","authors":"A.K. Bhattacharya","doi":"10.1016/0304-5102(94)00106-5","DOIUrl":null,"url":null,"abstract":"<div><p>The chemisorption and decomposition of benzene, cyclohexene and cyclohexane on clean and carbided Fe(110) surfaces has been studied by electron impact-induced Auger electron spectroscopy. Distinct and characteristic carbon (1s VV) Auger line-shapes of the three cyclic hydrocarbons molecularly adsorbed on a clean Fe(110) surface are reported. The thermal decomposition pathway of both benzene and cyclohexene have been followed and found to be similar. Cyclohexane has been found to desorb from the clean surface at well below room temperature without undergoing decomposition.</p></div>","PeriodicalId":16567,"journal":{"name":"分子催化","volume":"93 2","pages":"Pages 181-188"},"PeriodicalIF":0.0000,"publicationDate":"1994-10-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0304-5102(94)00106-5","citationCount":"1","resultStr":"{\"title\":\"High resolution Auger electron spectroscopic study of the chemisorption and decomposition of benzene, cyclohexene and cyclohexane on a clean and carbided Fe(110) surface\",\"authors\":\"A.K. Bhattacharya\",\"doi\":\"10.1016/0304-5102(94)00106-5\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>The chemisorption and decomposition of benzene, cyclohexene and cyclohexane on clean and carbided Fe(110) surfaces has been studied by electron impact-induced Auger electron spectroscopy. Distinct and characteristic carbon (1s VV) Auger line-shapes of the three cyclic hydrocarbons molecularly adsorbed on a clean Fe(110) surface are reported. The thermal decomposition pathway of both benzene and cyclohexene have been followed and found to be similar. Cyclohexane has been found to desorb from the clean surface at well below room temperature without undergoing decomposition.</p></div>\",\"PeriodicalId\":16567,\"journal\":{\"name\":\"分子催化\",\"volume\":\"93 2\",\"pages\":\"Pages 181-188\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"1994-10-13\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://sci-hub-pdf.com/10.1016/0304-5102(94)00106-5\",\"citationCount\":\"1\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"分子催化\",\"FirstCategoryId\":\"1089\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/0304510294001065\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q4\",\"JCRName\":\"Chemical Engineering\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"分子催化","FirstCategoryId":"1089","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/0304510294001065","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"Chemical Engineering","Score":null,"Total":0}
High resolution Auger electron spectroscopic study of the chemisorption and decomposition of benzene, cyclohexene and cyclohexane on a clean and carbided Fe(110) surface
The chemisorption and decomposition of benzene, cyclohexene and cyclohexane on clean and carbided Fe(110) surfaces has been studied by electron impact-induced Auger electron spectroscopy. Distinct and characteristic carbon (1s VV) Auger line-shapes of the three cyclic hydrocarbons molecularly adsorbed on a clean Fe(110) surface are reported. The thermal decomposition pathway of both benzene and cyclohexene have been followed and found to be similar. Cyclohexane has been found to desorb from the clean surface at well below room temperature without undergoing decomposition.
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