硫脲在氧化还原聚合中的作用

G. S. Misra, U. Bajpai, J. Trekoval
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引用次数: 10

摘要

摘要过氧化物类的有机和无机化合物在加成聚合引发中的应用是众所周知的。研究发现,少量助剂的加入使乙烯基单体的聚合反应容易发生。这种聚合被称为还原-氧化或氧化还原。这种反应的一个例子是众所周知的反应中羟基自由基的形成
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Role of Thiourea in Redox Polymerization
Abstract The use of organic and inorganic compounds belonging to the class of peroxides in the initiation of addition polymerization is well known. It has been found that the addition of small amounts of additives brings about the initiation of the polymerization of vinyl monomers with ease. Such polymerizations have been termed reduction-oxidation or redox. An example of such a reaction is the formation of hydroxy free radicals in the well-known reaction
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