{"title":"PbI2(乙二胺)2,catena-μ-乙二胺-乙二胺二碘铅(II)在-150℃下的晶体结构","authors":"Hiroaki Yamanaka, G. Hihara, H. Miyamae","doi":"10.2116/ANALSCIX.24.X121","DOIUrl":null,"url":null,"abstract":"The title complex is triclinic, P1, a = 7.585(3), b = 7.688(4), c = 12.737(6)A, α = 83.22(2), β = 73.731(19), γ = 63.38(2)°, V = 637.4(5)°3, and Z = 2 at -150°C; R is 0.0242. The structure shows a one-dimensional polymer extending along [111] with two crystallographically independent inversion centers lying at the middle of the C-C bond of each bridging ethylenediamine (en). The Pb atom is coordinated by two I atoms and four N atoms: the two I atoms occupy a cis-position, the two N atoms of a chelating en lie opposed to them, and the four atoms lie in a plane containing the Pb atom; the other two N atoms of the bridging en ligands lie at both axial positions. Since the I-Pb-I angle is 144.57(1)° wide, the Pb environment geometry might be described as being a distorted pentagonal bipyramid, providing a stereochemically active lone pair of electrons of the Pb atom may occupy one coordination site.","PeriodicalId":7796,"journal":{"name":"Analytical Sciences: X-ray Structure Analysis Online","volume":"34 5","pages":""},"PeriodicalIF":0.0000,"publicationDate":"2008-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"2","resultStr":"{\"title\":\"Crystal Structure of PbI2(ethylenediamine)2, catena-μ-Ethylenediamine-ethylenediaminediiodolead(II) at -150°C\",\"authors\":\"Hiroaki Yamanaka, G. Hihara, H. Miyamae\",\"doi\":\"10.2116/ANALSCIX.24.X121\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"The title complex is triclinic, P1, a = 7.585(3), b = 7.688(4), c = 12.737(6)A, α = 83.22(2), β = 73.731(19), γ = 63.38(2)°, V = 637.4(5)°3, and Z = 2 at -150°C; R is 0.0242. The structure shows a one-dimensional polymer extending along [111] with two crystallographically independent inversion centers lying at the middle of the C-C bond of each bridging ethylenediamine (en). The Pb atom is coordinated by two I atoms and four N atoms: the two I atoms occupy a cis-position, the two N atoms of a chelating en lie opposed to them, and the four atoms lie in a plane containing the Pb atom; the other two N atoms of the bridging en ligands lie at both axial positions. Since the I-Pb-I angle is 144.57(1)° wide, the Pb environment geometry might be described as being a distorted pentagonal bipyramid, providing a stereochemically active lone pair of electrons of the Pb atom may occupy one coordination site.\",\"PeriodicalId\":7796,\"journal\":{\"name\":\"Analytical Sciences: X-ray Structure Analysis Online\",\"volume\":\"34 5\",\"pages\":\"\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2008-01-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"2\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Analytical Sciences: X-ray Structure Analysis Online\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.2116/ANALSCIX.24.X121\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Analytical Sciences: X-ray Structure Analysis Online","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.2116/ANALSCIX.24.X121","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 2
摘要
标题配合物为三斜状,P1, a = 7.585(3), b = 7.688(4), c = 12.737(6) a, α = 83.22(2), β = 73.731(19), γ = 63.38(2)°,V = 637.4(5)°3,Z = 2;R是0.0242。该结构显示了沿[111]延伸的一维聚合物,在每个桥接的乙二胺(en)的C-C键的中间有两个晶体独立的反转中心。Pb原子由2个I原子和4个N原子配位:2个I原子处于顺式位置,2个N原子处于与之相反的一个螯合面,4个原子位于包含Pb原子的一个平面内;桥接配体的另外两个N原子位于两个轴向位置。由于I-Pb-I角为144.57(1)°宽,Pb环境的几何形状可以描述为一个扭曲的五边形双金字塔,提供了一个立体化学活性的铅原子的孤对电子可能占据一个配位位。
Crystal Structure of PbI2(ethylenediamine)2, catena-μ-Ethylenediamine-ethylenediaminediiodolead(II) at -150°C
The title complex is triclinic, P1, a = 7.585(3), b = 7.688(4), c = 12.737(6)A, α = 83.22(2), β = 73.731(19), γ = 63.38(2)°, V = 637.4(5)°3, and Z = 2 at -150°C; R is 0.0242. The structure shows a one-dimensional polymer extending along [111] with two crystallographically independent inversion centers lying at the middle of the C-C bond of each bridging ethylenediamine (en). The Pb atom is coordinated by two I atoms and four N atoms: the two I atoms occupy a cis-position, the two N atoms of a chelating en lie opposed to them, and the four atoms lie in a plane containing the Pb atom; the other two N atoms of the bridging en ligands lie at both axial positions. Since the I-Pb-I angle is 144.57(1)° wide, the Pb environment geometry might be described as being a distorted pentagonal bipyramid, providing a stereochemically active lone pair of electrons of the Pb atom may occupy one coordination site.