尿素再生的原丁腈橡胶和复合丁腈胶乳共混物的表征:第二部分-物理力学性能

K. Perera, D. Edirisinghe, L. Karunanayake
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引用次数: 1

摘要

回收橡胶废料以将其转化为可用产品是橡胶工业面临的主要挑战之一。由于对环境的日益关注和合成橡胶价格的上涨,过去橡胶废料的回收和与原始橡胶的混炼有所增加。因此,本研究的目的是用再生的复配丁腈橡胶胶乳废液部分替代原丁腈橡胶,以开发适合特殊用途的新型橡胶共混物。在这项研究中,评估了天然丁腈橡胶/再生丁腈橡胶共混硫化胶的物理力学性能、老化性能和膨胀行为,并与纯天然丁腈橡胶生产的对照硫化胶进行了比较。结果表明,用再生丁腈橡胶代替50%的原丁腈橡胶,其拉伸强度、断裂伸长率和回弹性仍保持71-86%。该共混硫化胶的硬度和模量增加不到18%,而磨损体积损失和压缩集料增加了27%。耐老化性与对照硫化胶相似。有趣的是,在甲苯和ASTM 3号油中,抗膨胀性分别提高了14%和32%。因此,50:50的原始丁腈橡胶/再生丁腈橡胶硫化胶将适用于耐油应用。
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Characterization of Blends of Virgin Nitrile Rubber and Compounded Nitrile Rubber Latex Waste Reclaimed with Urea: Part II - Physico-Mechanical Properties
Recycling of rubber waste materials in order to convert these to usable products is one of the main challenges in the rubber industry. Reclaiming of rubber waste and blending it with virgin rubber have increased during the past due to the growing concern on the environment and increase in the prices of synthetic rubbers. Hence, the aim of this study is to partially replace virgin nitrile rubber (NBR) with reclaimed compounded NBR latex waste to develop new rubber blends suitable for special applications. In this study, physico-mechanical properties, ageing performance and swelling behaviour of virgin NBR / reclaimed NBR blend vulcanizates were evaluated and compared with those of the control vulcanizate produced solely with virgin NBR. Results showed that replacement of 50% virgin NBR with reclaimed NBR retained 71-86% of tensile strength, elongation at break and resilience. Hardness and modulus of this blend vulcanizate increased by less than 18%, whereas abrasion volume loss and compression set increased by 27%. Ageing resistance is similar to that of the control vulcanizate. Interestingly, resistance to swelling in toluene and ASTM oil No.3 increased by 14% and 32%, respectively. Hence, the 50:50 virgin NBR / reclaimed NBR vulcanizate would be suitable for oil resistant applications.
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