低温气相和低温溶液中具有强分子间相互作用的系统的振动弛豫研究

K.S. Rutkovskiì, K.G. Tokhadze
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引用次数: 1

摘要

用红外荧光和双红外共振测量了CD3F和CD4在He、Ne、Ar、Kr、Xe和HCl混合气相和Ar、Kr、Xe液相中的V-T弛豫。结果表明,在350-150°K区间内,V-T概率的温度依赖性可归因于远程力的影响越来越大。在CD3F + HCl的混合物中,形成了CD3F…HCl的h键配合物,随着温度的降低,振动弛豫率显著增加。研究发现,低温溶液中V-T能量传递的概率比气相中低。
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Vibrational relaxation studies of systems with strong intermolecular interactions at low temperatures in the gas phase and in cryogenic solutions

Infrared fluorescence and double infrared resonance have been used to measure the V-T relaxation of CD3F and CD4 in mixtures with He, Ne, Ar, Kr, Xe and HCl in the gas phase and in the liquid Ar, Kr, Xe. It is shown that the temperature dependence of V-T probabilities in the interval 350–150°K can be attributed to an increasing influence of long range forces. In the mixture CD3F + HCl, where H-bonded complexes CD3F…HCl have been formed, the vibrational relaxation rate considerably increases with decreasing temperature. It is found that the probabilities of V-T energy transfer in cryogenic solutions are lower than those measured in the gas phae.

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