{"title":"铁(III)与乙醇酸和乳酸螯合的弛豫动力学研究。中间步骤对整个过程中极限速率的贡献","authors":"F.P. Cavasino, E. Di Dio, C. Sbriziolo","doi":"10.1016/0378-4487(82)80029-0","DOIUrl":null,"url":null,"abstract":"<div><p>The kinetics of formation of iron(III) monochelates with glycolic and lactic acids have been investigated by the temperature-jump method at 25.0°C and ionic strength 1.0 M over the acidity range 0.0200 – 0.900 M. The kinetic data indicate that two reaction paths, involving the FeOH<sup>2+</sup> ion and the neutral and anionic (HL-L<sup>−</sup>) forms of the ligands, lead to the iron(III) chelate formation and that the monodentate complex Fe(OH)L-LH<sup>+</sup> is formed as an intermediate compound. Moreover the observed [H<sup>+</sup>]-dependence of the forward rate constants permits us to estimate the contribution of intermediate steps to the limiting rate in the overall chelate formation process.</p></div>","PeriodicalId":100049,"journal":{"name":"Advances in Molecular Relaxation and Interaction Processes","volume":"23 3","pages":"Pages 191-201"},"PeriodicalIF":0.0000,"publicationDate":"1982-07-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0378-4487(82)80029-0","citationCount":"2","resultStr":"{\"title\":\"Relaxation kinetic study of iron(III) chelation with glycolic and lactic acids. Contribution of intermediate steps to the limiting rate in the overall process\",\"authors\":\"F.P. Cavasino, E. Di Dio, C. Sbriziolo\",\"doi\":\"10.1016/0378-4487(82)80029-0\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>The kinetics of formation of iron(III) monochelates with glycolic and lactic acids have been investigated by the temperature-jump method at 25.0°C and ionic strength 1.0 M over the acidity range 0.0200 – 0.900 M. The kinetic data indicate that two reaction paths, involving the FeOH<sup>2+</sup> ion and the neutral and anionic (HL-L<sup>−</sup>) forms of the ligands, lead to the iron(III) chelate formation and that the monodentate complex Fe(OH)L-LH<sup>+</sup> is formed as an intermediate compound. Moreover the observed [H<sup>+</sup>]-dependence of the forward rate constants permits us to estimate the contribution of intermediate steps to the limiting rate in the overall chelate formation process.</p></div>\",\"PeriodicalId\":100049,\"journal\":{\"name\":\"Advances in Molecular Relaxation and Interaction Processes\",\"volume\":\"23 3\",\"pages\":\"Pages 191-201\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"1982-07-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://sci-hub-pdf.com/10.1016/0378-4487(82)80029-0\",\"citationCount\":\"2\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Advances in Molecular Relaxation and Interaction Processes\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/0378448782800290\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Advances in Molecular Relaxation and Interaction Processes","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/0378448782800290","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Relaxation kinetic study of iron(III) chelation with glycolic and lactic acids. Contribution of intermediate steps to the limiting rate in the overall process
The kinetics of formation of iron(III) monochelates with glycolic and lactic acids have been investigated by the temperature-jump method at 25.0°C and ionic strength 1.0 M over the acidity range 0.0200 – 0.900 M. The kinetic data indicate that two reaction paths, involving the FeOH2+ ion and the neutral and anionic (HL-L−) forms of the ligands, lead to the iron(III) chelate formation and that the monodentate complex Fe(OH)L-LH+ is formed as an intermediate compound. Moreover the observed [H+]-dependence of the forward rate constants permits us to estimate the contribution of intermediate steps to the limiting rate in the overall chelate formation process.