三氟甲磺酸锌的制备及其性能研究

Tatsuko Takei
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引用次数: 1

摘要

制备了三氟甲烷磺酸锌(Zn(CF3SO3)2)。其纯度优于98.7%。锌盐在600℃以下不分解。在25℃条件下可溶于100g甲醇、乙醇、乙腈、N、N-二甲基甲酰胺和甲酰胺,用量分别为117 g、63.9 g、71.8 g、42.7 g和29.8 g。在甲醇溶液中最大电导率为300 μS cm-1。45°C无限稀释时,甲醇溶液的摩尔电导率为132 ω-1 cm2 mol-1,N,N-二甲基甲酰胺溶液为147 ω-1 cm2 mol-1,乙醇溶液为20.5 ω-1 cm2 mol-1,甲酰胺溶液为80 ω-1 cm2 mol-1,乙腈溶液为137 ω-1 cm2 mol-1。
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Preparation of zinc trifluoromethanesulphonate and its properties

Zinc trifluoromethanesulphonate (Zn(CF3SO3)2) was prepared. Its purity was better than 98.7%. The zinc salt did not decompose below 600 °C. It was soluble in 100 g of methanol, ethanol, acetonitrile, N,N-dimethyl formamide and formamide at 25 °C in amounts of 117 g, 63.9 g, 71.8 g, 42.7 g and 29.8 g respectively. A maximum conductivity of 300 μS cm-1 was observed in methanol solution. The molar conductivity at 45 °C at infinite dilution was 132 ω-1 cm2 mol-1 for methanol solution, 147 ω-1 cm2 mol-1 for N,N-dimethylformamide solution, 20.5 ω-1 cm2 mol-1 for ethanol solution, 80 ω-1 cm2 mol-1 formamide solution and 137 ω-1 cm2 mol-1 for acetonitrile solution.

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