{"title":"三氟甲磺酸锌的制备及其性能研究","authors":"Tatsuko Takei","doi":"10.1016/0376-4583(85)90089-5","DOIUrl":null,"url":null,"abstract":"<div><p>Zinc trifluoromethanesulphonate (Zn(CF<sub>3</sub>SO<sub>3</sub>)<sub>2</sub>) was prepared. Its purity was better than 98.7%. The zinc salt did not decompose below 600 °C. It was soluble in 100 g of methanol, ethanol, acetonitrile, <em>N,N</em>-dimethyl formamide and formamide at 25 °C in amounts of 117 g, 63.9 g, 71.8 g, 42.7 g and 29.8 g respectively. A maximum conductivity of 300 μS cm<sup>-1</sup> was observed in methanol solution. The molar conductivity at 45 °C at infinite dilution was 132 ω<sup>-1</sup> cm<sup>2</sup> mol<sup>-1</sup> for methanol solution, 147 ω<sup>-1</sup> cm<sup>2</sup> mol<sup>-1</sup> for <em>N,N</em>-dimethylformamide solution, 20.5 ω<sup>-1</sup> cm<sup>2</sup> mol<sup>-1</sup> for ethanol solution, 80 ω<sup>-1</sup> cm<sup>2</sup> mol<sup>-1</sup> formamide solution and 137 ω<sup>-1</sup> cm<sup>2</sup> mol<sup>-1</sup> for acetonitrile solution.</p></div>","PeriodicalId":22037,"journal":{"name":"Surface Technology","volume":"25 4","pages":"Pages 369-375"},"PeriodicalIF":0.0000,"publicationDate":"1985-08-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0376-4583(85)90089-5","citationCount":"1","resultStr":"{\"title\":\"Preparation of zinc trifluoromethanesulphonate and its properties\",\"authors\":\"Tatsuko Takei\",\"doi\":\"10.1016/0376-4583(85)90089-5\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>Zinc trifluoromethanesulphonate (Zn(CF<sub>3</sub>SO<sub>3</sub>)<sub>2</sub>) was prepared. Its purity was better than 98.7%. The zinc salt did not decompose below 600 °C. It was soluble in 100 g of methanol, ethanol, acetonitrile, <em>N,N</em>-dimethyl formamide and formamide at 25 °C in amounts of 117 g, 63.9 g, 71.8 g, 42.7 g and 29.8 g respectively. A maximum conductivity of 300 μS cm<sup>-1</sup> was observed in methanol solution. The molar conductivity at 45 °C at infinite dilution was 132 ω<sup>-1</sup> cm<sup>2</sup> mol<sup>-1</sup> for methanol solution, 147 ω<sup>-1</sup> cm<sup>2</sup> mol<sup>-1</sup> for <em>N,N</em>-dimethylformamide solution, 20.5 ω<sup>-1</sup> cm<sup>2</sup> mol<sup>-1</sup> for ethanol solution, 80 ω<sup>-1</sup> cm<sup>2</sup> mol<sup>-1</sup> formamide solution and 137 ω<sup>-1</sup> cm<sup>2</sup> mol<sup>-1</sup> for acetonitrile solution.</p></div>\",\"PeriodicalId\":22037,\"journal\":{\"name\":\"Surface Technology\",\"volume\":\"25 4\",\"pages\":\"Pages 369-375\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"1985-08-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://sci-hub-pdf.com/10.1016/0376-4583(85)90089-5\",\"citationCount\":\"1\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Surface Technology\",\"FirstCategoryId\":\"1087\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/0376458385900895\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Surface Technology","FirstCategoryId":"1087","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/0376458385900895","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Preparation of zinc trifluoromethanesulphonate and its properties
Zinc trifluoromethanesulphonate (Zn(CF3SO3)2) was prepared. Its purity was better than 98.7%. The zinc salt did not decompose below 600 °C. It was soluble in 100 g of methanol, ethanol, acetonitrile, N,N-dimethyl formamide and formamide at 25 °C in amounts of 117 g, 63.9 g, 71.8 g, 42.7 g and 29.8 g respectively. A maximum conductivity of 300 μS cm-1 was observed in methanol solution. The molar conductivity at 45 °C at infinite dilution was 132 ω-1 cm2 mol-1 for methanol solution, 147 ω-1 cm2 mol-1 for N,N-dimethylformamide solution, 20.5 ω-1 cm2 mol-1 for ethanol solution, 80 ω-1 cm2 mol-1 formamide solution and 137 ω-1 cm2 mol-1 for acetonitrile solution.