海洋沉积物概论,强调沉积物有机质再矿化作用

David J. Burdige
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引用次数: 1

摘要

发生在海洋沉积物上层几米的过程对许多元素的局部和全球循环有深远的影响。例如,沉积物中有机碳保存和再矿化之间的平衡代表了海洋、大气和陆地上活跃的地表储层中的碳循环与更长的地质时间尺度上的碳循环(即沉积岩、煤和石油矿床)之间的关键联系。了解发生在表层海洋沉积物中的过程对于准确解释古海洋学沉积物记录也很重要,因为沉积过程有时会显著改变沉积物中记录的原始“沉积”信号。在沿海和河口沉积物中,沉积物中的氮和磷再矿化可以提供水柱中初级生产者所需的大部分养分。同样,在受到某些有毒金属人为输入增加的沿海和河口沉积物中,沉积过程影响这些沉积物作为这些金属的“永久”或“临时”汇的程度。海洋沉积物的地球化学是由最初沉积在沉积物中的物质组成和沉积后影响这些物质的化学、生物或物理过程控制的。这些过程属于通常所说的早期成岩作用的一般范畴。海洋沉积物早期成岩作用研究的一个非常关键的方面是,沉积在沉积物中的有机质的氧化或再矿化是许多这些早期成岩变化的直接或间接诱因。鉴于有机质再矿化作用在许多早期成岩过程中起着关键作用,对这些过程的理解和量化已经取得了重大进展。本讲座将简要介绍海洋沉积物地球化学,重点介绍沉积物中有机质再矿化的基本控制因素。它是基于我最近给本科生地质学课上的一堂地层学讲座。我相信它在普通海洋学、低温地球化学或环境地球化学的本科课程中也会很有用。海洋沉积物的地球化学是由最初沉积在沉积物中的物质组成和沉积后影响这些物质的化学、生物或物理过程控制的。这些过程属于通常所说的早期成岩作用的一般范畴。海洋沉积物早期成岩作用研究的一个关键方面是,沉积物有机质的氧化或再矿化是许多早期成岩变化的直接或间接诱因。由于有机质再矿化作用在早期成岩过程中起着关键作用,对这一过程的理解和量化已经取得了重大进展。本讲座将简要介绍海洋沉积物地球化学,重点介绍沉积物中有机质再矿化的基本控制因素。我相信这堂课对普通海洋学、低温地球化学或环境地球化学的本科课程很有帮助。在这两个领域的研究生入门课程中,它也很有用。
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An Introduction to Marine Sediments with an Emphasis on Sediment Organic Matter Remineralization

The processes occurring in the upper several meters of marine sediments have a profound effect on the local and global cycling of many elements. For example, the balance between organic carbon preservation and remineralization in sediments represents the key link between carbon cycling in active, surface reservoirs in the oceans, atmosphere, and on land, and carbon that cycles on much longer, geological time scales, i.e., in sedimentary rock, and in coal and petroleum deposits. Understanding processes occurring in surficial marine sediment is also important in the accurate interpretation of paleoceanographic sediment records, since sediment processes can sometimes significantly alter the primary “depositional” signal recorded in the sediments. In coastal and estuarine sediments nitrogen and phosphorus remineralization in the sediments can provide a significant fraction of the nutrients required by primary producers in the water column. Similarly, in coastal and estuarine sediments subjected to elevated anthropogenic inputs of certain toxic metals, sediment processes affect the extent to which these sediments represent “permanent” versus “temporary” sinks for these metals.

The geochemistry of marine sediments is controlled by both the composition of the material initially deposited in the sediments and the chemical, biological or physical processes that affect this material after its deposition. These processes fall within the general category of what is commonly referred to as early diagenesis. One very crucial aspect of the study of early diagenesis in marine sediments is that the oxidation, or remineralization, of organic matter deposited in the sediments is either the direct or indirect causative agent for many of these early diagenetic changes. Given this pivotal role that organic matter remineralization plays in many early diagenetic processes, significant efforts have gone into understanding and quantifying these processes.

This lecture provides a brief introduction to marine sediment geochemistry focusing on the basic controls on organic matter remineralization in sediments. It is based on a lecture I recently gave to an undergraduate geology class in stratigraphy. I believe that it could also be useful in an undergraduate class in general oceanography, low temperature geochemistry or environmental geochemistry.

Lecture summary

The geochemistry of marine sediments is controlled by both the composition of the material initially deposited in the sediments and the chemical, biological or physical processes that affect this material after its deposition. These processes fall within the general category of what is commonly referred to as early diagenesis. One key aspect of the study of early diagenesis in marine sediments is that the oxidation, or remineralization, of sediment organic matter is either the direct or indirect causative agent for many early diagenetic changes.

Given the pivotal role that organic matter remineralization plays in early diagenetic processes, significant efforts have gone into understanding and quantifying these processes. This lecture provides a brief introduction to marine sediment geochemistry, focusing on the basic controls of organic matter remineralization in sediments. I believe that the lecture could be useful in an undergraduate class in general oceanography, low temperature geochemistry or environmental geochemistry. It could also be useful in introductory graduate classes in these latter two areas.

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