{"title":"丙炔氧化的实验与动力学模拟研究","authors":"S.G. Davis , C.K. Law , H. Wang","doi":"10.1016/S0082-0784(98)80417-7","DOIUrl":null,"url":null,"abstract":"<div><p>The oxidation of propyne was studied experimentally in an atmospheric-pressure flow reactor and in laminar premixed flames. Species profiles were obtained for propyne oxidation experiments conducted in the Princeton turbulent flow reactor (PTFR) in the intermediate- to high-temperature range (∼1170 K) for lean, stoichiometric, and rich conditions. Laminar flame speeds of propyne/(18% O<sub>2</sub> in N<sub>2</sub>) mixtures were determined, over an extensive range of equivalence ratios, at room temperature and atmospheric pressure, using the counterflow twin flame configuration. A detailed chemical kinetic model of high-temperature propyne oxidation, consisting of 437 reactions and 69 species, was developed. It is shown that this kinetic model predicts reasonably well the flow-reactor and flame-speed data determined in this study and the shock tube ignition data available in the literature. The remaining uncertainties in the reaction kinetics of propyne oxidation are discussed.</p></div>","PeriodicalId":101203,"journal":{"name":"Symposium (International) on Combustion","volume":"27 1","pages":"Pages 305-312"},"PeriodicalIF":0.0000,"publicationDate":"1998-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/S0082-0784(98)80417-7","citationCount":"33","resultStr":"{\"title\":\"An experimental and kinetic modeling study of propyne oxidation\",\"authors\":\"S.G. Davis , C.K. Law , H. Wang\",\"doi\":\"10.1016/S0082-0784(98)80417-7\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>The oxidation of propyne was studied experimentally in an atmospheric-pressure flow reactor and in laminar premixed flames. Species profiles were obtained for propyne oxidation experiments conducted in the Princeton turbulent flow reactor (PTFR) in the intermediate- to high-temperature range (∼1170 K) for lean, stoichiometric, and rich conditions. Laminar flame speeds of propyne/(18% O<sub>2</sub> in N<sub>2</sub>) mixtures were determined, over an extensive range of equivalence ratios, at room temperature and atmospheric pressure, using the counterflow twin flame configuration. A detailed chemical kinetic model of high-temperature propyne oxidation, consisting of 437 reactions and 69 species, was developed. It is shown that this kinetic model predicts reasonably well the flow-reactor and flame-speed data determined in this study and the shock tube ignition data available in the literature. The remaining uncertainties in the reaction kinetics of propyne oxidation are discussed.</p></div>\",\"PeriodicalId\":101203,\"journal\":{\"name\":\"Symposium (International) on Combustion\",\"volume\":\"27 1\",\"pages\":\"Pages 305-312\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"1998-01-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://sci-hub-pdf.com/10.1016/S0082-0784(98)80417-7\",\"citationCount\":\"33\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Symposium (International) on Combustion\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0082078498804177\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Symposium (International) on Combustion","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0082078498804177","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 33
摘要
在常压流动反应器和层流预混火焰中对丙烯的氧化进行了实验研究。在普林斯顿湍流反应器(PTFR)中至高温范围内(~ 1170 K)，在稀薄、化学计量和丰富的条件下进行丙炔氧化实验，获得了物种分布。在室温和常压下，使用逆流双火焰配置，在广泛的等效比范围内，测定了丙炔/(18% O2 in N2)混合物的层流火焰速度。建立了包含437个反应、69种物质的高温丙炔氧化化学动力学模型。结果表明，该动力学模型可以较好地预测本研究确定的流动反应器和火焰速度数据以及文献中已有的激波管点火数据。讨论了丙炔氧化反应动力学中存在的不确定因素。
An experimental and kinetic modeling study of propyne oxidation
The oxidation of propyne was studied experimentally in an atmospheric-pressure flow reactor and in laminar premixed flames. Species profiles were obtained for propyne oxidation experiments conducted in the Princeton turbulent flow reactor (PTFR) in the intermediate- to high-temperature range (∼1170 K) for lean, stoichiometric, and rich conditions. Laminar flame speeds of propyne/(18% O2 in N2) mixtures were determined, over an extensive range of equivalence ratios, at room temperature and atmospheric pressure, using the counterflow twin flame configuration. A detailed chemical kinetic model of high-temperature propyne oxidation, consisting of 437 reactions and 69 species, was developed. It is shown that this kinetic model predicts reasonably well the flow-reactor and flame-speed data determined in this study and the shock tube ignition data available in the literature. The remaining uncertainties in the reaction kinetics of propyne oxidation are discussed.
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