Efficient degradation of tetrabromobisphenol A using peroxymonosulfate oxidation activated by a novel nano-CuFe2O4@coconut shell biochar catalyst.

Abstract

In this study, a novel bimetallic complexation-curing nucleation-anaerobic calcination method was developed to synthesize a nano-CuFe₂O₄@coconut shell biochar (CuFe₂O₄@CSBC) catalyst to activate peroxymonosulfate for degradation of tetrabromobisphenol A (TBBPA). The reaction processes of the TBBPA on CuFe₂O₄@CSBC have been investigated using in situ characterization and metal leaching. The effects of initial reaction conditions and degradation mechanism were investigated. Greater than 99% degradation of TBBPA at 10 mg L^-1 was achieved in 30 min under the condition of pH 11, a total organic carbon removal rate of up to 70.67% was achieved and the degradation efficiency was 90% after 5 cycles of CuFe₂O₄@CSBC use. The degradation was in a second-order reaction at a constant of 0.797 M^-1 min^-1 (R² = 0.993). The degradation was attributed to the main active species (SO₄·^-≈·OH < ¹O₂), and the surface active site of CuFe₂O₄@CSBC was the key role. The degradation process involved three main degradation pathways. Path A: ·OH attacked the C-Br bonds (TBBPA→TriBBPA→DBBPA→MBBPA→BPA); Path B: Hydroxylation and decarboxylation; Path C: Dehydrocoupling of TBBPA. What's more, the practical application of the system was very positive, achieved >77% degradation in sewage and industrial wastewater.