Conductivity, its anisotropy and changes as a manifestation of the features of the atomic and real structures of superprotonic [K_1-x(NH₄)_x]₃H(SO₄)₂ crystals.

IF 16.4 1区化学 Q1 CHEMISTRY, MULTIDISCIPLINARY Accounts of Chemical Research Pub Date : 2023-02-01 DOI:10.1107/S2052520622011751

Elena Selezneva, Irina Makarova, Radmir Gainutdinov, Alla Tolstikhina, Inna Malyshkina, Nikolai Somov, Evgeniy Chuprunov

{"title":"Conductivity, its anisotropy and changes as a manifestation of the features of the atomic and real structures of superprotonic [K1-x(NH4)x]3H(SO4)2 crystals.","authors":"Elena Selezneva, Irina Makarova, Radmir Gainutdinov, Alla Tolstikhina, Inna Malyshkina, Nikolai Somov, Evgeniy Chuprunov","doi":"10.1107/S2052520622011751","DOIUrl":null,"url":null,"abstract":"Single crystals of [K1-x(NH4)x]3H(SO4)2 (x ≥ 0.57) grown in the K3H(SO4)2-(NH4)3H(SO4)2-H2O water-salt system are studied. The atomic structure including H atoms was determined at room temperature using X-ray structural analysis. [K1-x(NH4)x]3H(SO4)2 (x ≥ 0.57) crystals have trigonal symmetry and disordered hydrogen-bond networks at ambient conditions similar to the high-temperature phases of K3H(SO4)2, (NH4)3H(SO4)2 and other superprotonic compounds M3H(AO4)2. Impedance measurements performed on single crystals show high values of conductivity characteristic for superprotonic phases. Using the methods of impedance spectroscopy and atomic force microscopy, a significant anisotropy of the conductivity of crystals has been detected. It was also shown that there is a qualitative correlation of bulk and local conductivity measured for samples of the same composition and orientation at room temperature, which is due to the peculiarities of their crystal structure.","PeriodicalId":1,"journal":{"name":"Accounts of Chemical Research","volume":null,"pages":null},"PeriodicalIF":16.4000,"publicationDate":"2023-02-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Accounts of Chemical Research","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.1107/S2052520622011751","RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}

引用次数: 0

Abstract

Single crystals of [K_1-x(NH₄)_x]₃H(SO₄)₂ (x ≥ 0.57) grown in the K₃H(SO₄)₂-(NH₄)₃H(SO₄)₂-H₂O water-salt system are studied. The atomic structure including H atoms was determined at room temperature using X-ray structural analysis. [K_1-x(NH₄)_x]₃H(SO₄)₂ (x ≥ 0.57) crystals have trigonal symmetry and disordered hydrogen-bond networks at ambient conditions similar to the high-temperature phases of K₃H(SO₄)₂, (NH₄)₃H(SO₄)₂ and other superprotonic compounds M₃H(AO₄)₂. Impedance measurements performed on single crystals show high values of conductivity characteristic for superprotonic phases. Using the methods of impedance spectroscopy and atomic force microscopy, a significant anisotropy of the conductivity of crystals has been detected. It was also shown that there is a qualitative correlation of bulk and local conductivity measured for samples of the same composition and orientation at room temperature, which is due to the peculiarities of their crystal structure.

Abstract Image

查看原文

微信好友朋友圈 QQ好友复制链接

本刊更多论文

电导率及其各向异性及其变化是超质子[K1-x(NH4)x]3H(SO4)2晶体原子结构和实际结构特征的表现。

研究了在K3H(SO4)2-(NH4)3H(SO4)2- h2o水盐体系中生长的[K1-x(NH4)x]3H(SO4)2 (x≥0.57)单晶。在室温下用x射线结构分析确定了含H原子的原子结构。[K1-x(NH4)x]3H(SO4)2 (x≥0.57)晶体在环境条件下具有与K3H(SO4)2、(NH4)3H(SO4)2和其他超质子化合物M3H(AO4)2的高温相相似的三角对称和无序氢键网络。在单晶上进行的阻抗测量显示，超质子相的电导率特性值很高。利用阻抗谱和原子力显微镜的方法，发现了晶体电导率的显著各向异性。研究还表明，在室温下，相同成分和取向的样品的体积和局部电导率具有定性的相关性，这是由于它们的晶体结构的特殊性。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

求助全文

约1分钟内获得全文去求助

来源期刊

Accounts of Chemical Research 化学-化学综合

CiteScore

31.40

自引率

1.10%

发文量

312

审稿时长

2 months

期刊介绍： Accounts of Chemical Research presents short, concise and critical articles offering easy-to-read overviews of basic research and applications in all areas of chemistry and biochemistry. These short reviews focus on research from the author’s own laboratory and are designed to teach the reader about a research project. In addition, Accounts of Chemical Research publishes commentaries that give an informed opinion on a current research problem. Special Issues online are devoted to a single topic of unusual activity and significance. Accounts of Chemical Research replaces the traditional article abstract with an article "Conspectus." These entries synopsize the research affording the reader a closer look at the content and significance of an article. Through this provision of a more detailed description of the article contents, the Conspectus enhances the article's discoverability by search engines and the exposure for the research.