Pyrite contact twins.

IF 16.4 1区 化学 Q1 CHEMISTRY, MULTIDISCIPLINARY Accounts of Chemical Research Pub Date : 2023-02-01 DOI:10.1107/S2052520622011714
Yves Moëlo, Massimo Nespolo, François Farges
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引用次数: 1

Abstract

Two examples of contact twins in pyrite from Peru are described. The first one, from Pasto Bueno ore deposit, shows the pyritohedron {120} as principal form, accompanied by the {111} octahedron and {100} cube as secondary forms, giving a lenticular aspect. (111) is the composition plane, and the twin operation is any one of the three binary axes ⟨110⟩ within this plane. The second one (unknown ore deposit) presents two forms, the octahedron {111} and the pyritohedron {120}; the two crystals in the twin are elongated along [101] and [011], respectively, producing a V profile. It is a reflection twin where the twin plane (110) coincides with the composition plane. These twins are by merohedry. Another contact twin is known in the literature, reported by Gaubert [Bull. Soc. Fr. Minéral. Cristallogr. (1928), 51, 211-212] who described it as a spinel twin, i.e. a reflection twin with twin and composition plane (111); here it is shown that it is actually a rotation twin in which the twin operation is a 180° rotation about any of the three equivalent directions ⟨211⟩, contained in the (111) composition plane. The occurrence of these twins as well as the doubtfulness of the spinel twin in pyrite shows a direct relationship with the structural interpretation based on the pseudo-symmetry of the crystallographic orbits.

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黄铁矿接触孪晶。
介绍了秘鲁黄铁矿中接触孪晶的两个例子。第一个是在Pasto Bueno矿床,以{120}为主要体型,{111}八面体和{100}立方体为次要体型,呈透镜状。(111)是合成平面,twin操作是该平面内的三个二进制轴⟨110⟩中的任何一个。第二种(未知矿床)呈现八面体{111}和核面体{120}两种形式;孪晶中的两个晶体分别沿[101]和[011]拉长,形成V型轮廓。它是一个反射孪晶,孪晶平面(110)与合成平面重合。这对双胞胎是天生的。另一种接触双胞胎在文献中是已知的,由Gaubert [Bull]报道。Soc。Fr,矿物。Cristallogr。(1928), 51,211 -212]将其描述为尖晶石孪晶,即具有孪晶和组成平面的反射孪晶(111);这里显示它实际上是一个旋转孪生,其中孪生操作是围绕(111)组合平面中⟨211⟩的三个等效方向中的任何一个180°旋转。黄铁矿中尖晶石孪晶的出现以及尖晶石孪晶的不确定性与基于晶体轨道拟对称的结构解释有直接关系。
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来源期刊
Accounts of Chemical Research
Accounts of Chemical Research 化学-化学综合
CiteScore
31.40
自引率
1.10%
发文量
312
审稿时长
2 months
期刊介绍: Accounts of Chemical Research presents short, concise and critical articles offering easy-to-read overviews of basic research and applications in all areas of chemistry and biochemistry. These short reviews focus on research from the author’s own laboratory and are designed to teach the reader about a research project. In addition, Accounts of Chemical Research publishes commentaries that give an informed opinion on a current research problem. Special Issues online are devoted to a single topic of unusual activity and significance. Accounts of Chemical Research replaces the traditional article abstract with an article "Conspectus." These entries synopsize the research affording the reader a closer look at the content and significance of an article. Through this provision of a more detailed description of the article contents, the Conspectus enhances the article's discoverability by search engines and the exposure for the research.
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