Special Features of the Preliminary γ-Irradiation Influence on Photoluminescence of Multi-Component Silicate Glasses

M.A. Kasymdzhanov, S.S. Kasimova, S.S. Kurbanov, P.K. Khabibullaev
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引用次数: 2

Abstract

In multi-component silicate glasses, under the UV-excitation, time-resolved luminescence spectra were observed. These spectra occupied the region of 350–700 nm. The dynamics of changes in radiation induced absorption and spectral-kinetic characteristics of luminescence of γ-irradiation glasses at the expiry of prolonged time were studied. It is assumed that the luminescence in these glasses is caused by quasi-molecular compelxe centers which include the elements of base substance and impurity atom. These centers can appear in the glass both in the process of its melting and under the action of ionizing radiation. It is shown that, the centers of different origin are characterized by different spectral-kinetic properties of their photoluminescence.

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初步γ辐照对多组分硅酸盐玻璃光致发光影响的特殊性
在多组分硅酸盐玻璃中,在紫外激发下观察到时间分辨发光光谱。这些光谱分布在350 ~ 700 nm范围内。研究了γ辐照玻璃在长时间失效时辐射诱导吸收变化的动力学和发光光谱动力学特性。推测这些玻璃的发光是由含有碱基元素和杂质原子的准分子络合物中心引起的。这些中心既可以在玻璃熔化过程中出现,也可以在电离辐射作用下出现。结果表明,不同来源的中心具有不同的光致发光光谱动力学性质。
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