Glass-Ceramics Produced by Vitrification of Coal Fly Ash

B. Angjusheva, E. Fidančevska
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Abstract

Glass-ceramics based on CAS (CaO-Al2O3-SiO2) system was produced by controlled crystallization of vitrified fly ash. Fly ash was pre-treated by magnetic separation and nonmagnetic part of fly ash (NFA) was used. Maximal crystallization of parent glass occurs in the temperature region from 900 oC to 1160 oC. Glass-ceramics was produced by consolidation of parent glass i.e. pressing (45 MPa) and sintering at 950, 1000, 1050 and 1100 oC, and isothermal time at the final temperature of 30, 60, 120 minutes. The dominant crystalline phase was calcium aluminum silicate (anorthite). The obtained glass-ceramics could be potentially used in construction applications.
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粉煤灰玻璃化制备微晶玻璃
采用玻璃化粉煤灰控制结晶法制备CAS (CaO-Al2O3-SiO2)微晶玻璃。采用磁选法对粉煤灰进行预处理,利用粉煤灰的非磁性部分(NFA)。母玻璃的最大结晶发生在900 ~ 1160℃的温度范围内。通过对母玻璃进行45 MPa压实和950、1000、1050、1100℃烧结,最终温度分别为30、60、120 min等温时间制备微晶玻璃。主要晶相为钙铝硅酸盐(钙长石)。所获得的微晶玻璃具有潜在的建筑应用价值。
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