Chemical extraction of Biodiesel and Parametric analysis of DI-Diesel Engine using Algae esterified Oil-Gasoline Blends

R. Kumar, P. MURTHY G
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Abstract

Of late, the automobiles of all categories are massively increasing which aggravates the dependency on fossil fuel thus, the accessibility of petro-fuel decreases relentlessly. Under these circumstances, the investigations are taking new dimensions to find alternative, renewable with cost-effective fuel exclusively biofuels. However, a newer approach has been attempted for the production of biodiesel from wild stuff of Spirulina algae which is explored directly in its aquatic systems of the natural environment. The chemical extraction process was attempted with wild biomass of algae via pre-treatment for obtaining promising lipid content then; the algal oil (lipid) was subjected to the production of biodiesel through sequential transesterification reactions. The obtained biodiesel was measured as 94.65% produced from 0.920kg of algal oil extracted out of 1.6kg of algal biomass in a stipulated duration of time (2.50hr) taken for attaining maximum temperature. Further, the produced biodiesel was evaluated for its distinctive properties and the outcomes were compared with ASTM standard specifications. All the results appeared to be within the standards limit thereby, the methodical analysis was done for the performance and emission parameters via interacting algal biodiesel in the experimental (DI) diesel engine test-rig configured with a variable injection pressure of 210, 220 & 230 respectively. The blending ratio of algal diesel and gasoline (AB10 & AB 20v/v) were prepared based on volume and the results were correlated with petro-diesel. The physico-chemical parameters like color, odour, viscosity, density, total acid number, initial boiling point, flash point, calorific value, cetane number etc. were found to be significant when compared with petro-fuel. Correspondingly, the interactive parameters like flash point, pour point, cloud point, carbon residue, sulfur, ash, and water contents were correlated with the standard specifications. The substantial approach was observed in emission characteristics such as hydrocarbon (HC), carbon monoxide (CO), oxides of nitrogen (NOX) respectively in engine-algal fuel interactions. Whereas, a slight increase than petro-diesel with respect to sulfur oxide (SOX) emission and smoke opacity were also recorded. However, the marginal increase in Brake specific fuel consumption (BSFC) and Brake thermal efficiency (BTE) was noticed and the brake power (BP) was found slightly lower than petro-diesel. In conclusion, the protocol of producing biodiesel from wild stuff biomass of Spirulina maxima was found to be techno-economically feasible and this potential algal biodiesel can be recommended for the current engine applications without any alterations.
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生物柴油的化学提取及藻类酯化油-汽油混合物柴油发动机的参数分析
近年来,各类汽车大量增加,加剧了对化石燃料的依赖,因此,石油燃料的可及性不断下降。在这种情况下,研究正在从新的角度寻找可替代的、可再生的、具有成本效益的燃料,特别是生物燃料。然而,人们已经尝试了一种新的方法,即直接在自然环境的水生系统中利用野生螺旋藻生产生物柴油。对野生藻类生物量进行预处理,尝试化学提取工艺,获得了较好的油脂含量;藻类油(脂)通过连续酯交换反应生产生物柴油。在达到最高温度的规定时间(2.50小时)内,从1.6千克藻类生物质中提取0.920千克藻类油,得到94.65%的生物柴油。此外,对所生产的生物柴油的独特性能进行了评估,并将结果与ASTM标准规范进行了比较。在分别设置210、220和230可变喷射压力的实验(DI)柴油机试验台上,通过相互作用的藻类生物柴油对其性能和排放参数进行了系统分析。以体积为基础,确定了藻类柴油与汽油的混合比例(AB10和ab20v /v),并将结果与汽油柴油进行了相关性分析。与石油燃料相比,其理化参数如颜色、气味、粘度、密度、总酸值、初沸点、闪点、热值、十六烷值等具有重要意义。相应的,闪点、倾点、浊点、残碳、硫、灰分、含水量等交互参数与标准规范相关。在发动机-藻类燃料相互作用过程中,分别观察了碳氢化合物(HC)、一氧化碳(CO)和氮氧化物(NOX)的排放特征。然而,与汽油柴油相比,硫氧化物(SOX)排放和烟雾透明度也略有增加。然而,制动比油耗(BSFC)和制动热效率(BTE)的边际增加被注意到,制动功率(BP)被发现略低于汽油柴油。综上所述,从野生最大螺旋藻生物量生产生物柴油的方案在技术经济上是可行的,这种潜在的藻类生物柴油可以在不做任何改变的情况下推荐用于当前的发动机应用。
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