Numerical Simulation of Micronized Re-burning (MCR) Organic Acid Salt Used as an Accelerator

Manyin Hu, Xiuhong Wang, Zhong Liu, Yong Yang
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Abstract

The reaction mechanism of micronized coal re-burning (MCR) organic acid salt used as an accelerator had been described by 81 substances and 564 elementary reactions in this paper. And also the CHEMKIN software had been used to simulate the condition above. In the process of simulation of CHEMKIN, we used acetone as a substitute for Calcium Magnesium Acetate( CMA )to predigest. The results showed as follows: With the rising of the temperature, the falling of re-burning fuel ratio, the increasing of excess air coefficient in re-burning zone and the decreasing of calcium-sulfur ratio, the removal efficiency of NO decreases gradually; While the initiative concentration of SO2 increases 100ppm at a time, the content of NO decreases 12ppm, which restrains the generation of NO.
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微粉化再燃(MCR)有机酸盐促进剂的数值模拟
本文用81种物质和564种元素反应描述了微粉煤再燃有机酸盐作为促进剂的反应机理。并利用CHEMKIN软件对上述条件进行了模拟。在CHEMKIN模拟过程中,我们使用丙酮代替醋酸钙镁(CMA)进行预消化。结果表明:随着温度的升高、再燃燃料比的降低、再燃区多余空气系数的增大和钙硫比的降低,NO的脱除效率逐渐降低;SO2的初始浓度每增加100ppm, NO的含量每减少12ppm,抑制了NO的生成。
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