Hydrogen Diffusion Concentration Behaviors for Square Groove Weld Joint

T. Ohmi, A. Yokobori, G. Ozeki, T. Kasuya, N. Ishikawa, S. Minamoto, M. Enoki
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Abstract

Hydrogen induced cracking occurs at the welded position of the structure due to concentration of hydrogen during cooling process of welding. A square groove weld joint is one of typical one in engineering field. Hydrogen embrittlement cracking is sometimes caused during cooling process of a weld joint. For such case, hydrogen diffusion and concentration behaviour is a significant factor. One of authors has been proposed α multiplication method which magnifies the hydrogen driving term in the diffusion equation to find out detailed behaviours of hydrogen concentration around a local stress field. In this paper, to clarify hydrogen diffusion behaviour in the square groove weld joint, a coupled analysis of heat transfer – thermal stress – hydrogen diffusion combining with α multiplication method was conducted. From these results, it was found out that for the case of a square groove weld joint, since thermal stress was not highly localized for the case of using usual value of thermal expansion coefficient of steel, hydrogen concentration behaviour is not typical. However, if thermal stress is highly localized, hydrogen was found to be localized in the side of HAZ (heat affected zone) at the interface of WM (weld metal) and HAZ and is much more typical near the outer surface side of weld joint. Hydrogen diffusion and concentration behaviours were also found to be dominated not only by local thermal stress gradient, ∇σ but also by diffusion coefficient gradient, ∇D caused by temperature difference during cooling process. In this paper, effects of these factors on hydrogen concentration were investigated based on a coupled analysis of heat transfer – thermal stress – hydrogen diffusion combining with α multiplication method.
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方坡口焊接接头氢扩散集中行为
在焊接冷却过程中,由于氢气的富集,导致结构的焊接部位产生氢致开裂。方坡口焊接接头是工程领域中典型的焊接接头之一。焊接接头在冷却过程中有时会产生氢脆裂纹。在这种情况下,氢的扩散和浓度行为是一个重要的因素。作者提出了放大扩散方程中氢驱动项的α乘法法,以求得局部应力场周围氢浓度的详细行为。为了阐明方坡口焊接接头中氢的扩散行为,结合α乘法法进行了传热-热应力-氢扩散的耦合分析。从这些结果中发现,对于方坡口焊接接头,由于使用通常的钢热膨胀系数时,热应力不高度局部化,氢浓度行为不典型。而在热应力高度局部化的情况下,氢主要集中在热影响区(HAZ)一侧的焊缝金属与热影响区交界面处,且在焊缝外表面附近更为典型。氢气的扩散和浓度行为不仅受局部热应力梯度∇σ的影响,还受冷却过程中温差引起的扩散系数梯度∇D的影响。本文采用传热-热应力-氢扩散耦合分析方法,结合α乘法法,研究了这些因素对氢气浓度的影响。
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