Production of ink containing thermochromic dyestuff

Oya Aydın Urucu, Hatice Birtane
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Abstract

Security inks are functional inks containing a binder and a special colorant used in money, checks and valuable documents. In security inks, thermochromic dyes, UV emitted, infrared emitted dyes can be used. Thermochromic dyestuffs provide different colors at different temperatures and ensure the requirements in the field of security. Thermochromic inks are generally used in smart packaging applications, high temperature alarms and security inks. Thermochromic dyes are generally metalcontaining chemical materials. In this study, ink will be produced for metal surfaces by using commercial thermochromic dyestuff and it will be provided to act as a temperature warning plate. For this purpose, UV spectra of the thermochromic dyestuff was determinate with different temperature. Solvent-based ink with polyurethane binder containing 1; 3; 5% commercial thermochromic substance was produced. Screen prints were made on the metal surface with the produced ink. The color and gloss properties of the prints were measured with a spectrophotometer and glossmeter, respectively, at different temperatures. Print quality and surface properties were determined with an optical microscope. In addition, alkali, nitro, acid resistance tests were carried out. The reusability (color change) number was determined depending on how many temperature changes the print has. As a result, inks that change color at 38 °C with commercial thermochromic material were produced and successfully printed.
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生产含热致变色染料的油墨
防伪油墨是一种含有粘合剂和特殊着色剂的功能性油墨,用于钞票、支票和贵重文件。在防伪油墨中,可采用热致变色染料、紫外发射染料、红外发射染料。热致变色染料在不同的温度下提供不同的颜色,保证了安全领域的要求。热致变色油墨一般用于智能包装应用、高温报警和防伪油墨。热致变色染料一般是含金属的化学材料。在本研究中,将使用商用热致变色染料为金属表面生产油墨,并将其作为温度警告板。为此,对热致变色染料在不同温度下的紫外光谱进行了测定。溶剂型油墨用聚氨酯粘结剂含1;3;生产了5%的商用热致变色物质。丝网印刷是用生产出来的油墨在金属表面上进行的。用分光光度计和光泽度计分别测定了不同温度下印品的颜色和光泽度。用光学显微镜测定印品质量和表面特性。此外,还进行了耐碱、耐硝、耐酸试验。可重用性(颜色变化)数量取决于印刷品的温度变化次数。因此,用商用热致变色材料制成的在38°C下变色的油墨被生产出来并成功印刷。
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