Self-Powered Mechanical Energy Sensor Application of SnO2/Ag and PMMA/ITO Nanocomposites via Triboelectric Effect

G. Durak Yüzüak, M. Çetin, E. Yüzüak
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Abstract

The triboelectric nanogenerator is a state-of-the-art device for addressing the growing problem of meeting the world's ever-increasing energy needs by converting mechanical energy into electrical energy. Using the popular semiconductor SnO2 nanostructured thin films as a triboelectric layer over contact regions, as opposed to polymers with lesser performance, increases the output power and life time of nanogenerators. In order to design a triboelectric nanogenerator, deposited thin film SnO2 is used as a friction layer with Ag electrode after heat-treatment at 623 K with a contrary layer of PMMA poly (methyl-methacrylate) with ITO electrode. The structural and electrical properties were analyzed by using scanning electron microscopy (SEM), electro-impedance spectroscopy (EIS) and atomic force microscopy (AFM) measurements. The increased output power of the triboelectric nanogenerator is attributed to the nanoscale PMMA contact charge created by tunneling electrons in the SnO2/Ag nanocomposite thin film layer. Due to its proximity to the PMMA/ITO surface, the SnO2/Ag layer causes electron field emission, and tapping the SnO2/Ag layer may result in electron cloud overlap. Similar to a semiconductor/insulator interface, the Fermi level of SnO2 plays a crucial role in electron transport. The system efficiency stated as a touch detector in a conventional keyboard that generates its own power is revealed in part by an analysis of its operating state up to the 4V.
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基于摩擦电效应的SnO2/Ag和PMMA/ITO纳米复合材料自供电机械能传感器的应用
摩擦电纳米发电机是一种最先进的设备,通过将机械能转化为电能来解决日益增长的问题,以满足世界上不断增长的能源需求。使用流行的半导体SnO2纳米结构薄膜作为接触区域的摩擦电层,而不是性能较差的聚合物,增加了纳米发电机的输出功率和寿命。为了设计摩擦电纳米发电机,在623 K下热处理后,用沉积的SnO2薄膜作为Ag电极的摩擦层,用PMMA聚甲基丙烯酸甲酯作为ITO电极的摩擦层。采用扫描电子显微镜(SEM)、电阻抗谱(EIS)和原子力显微镜(AFM)对其结构和电学性能进行了分析。摩擦电纳米发电机输出功率的增加是由于在SnO2/Ag纳米复合薄膜层中隧穿电子产生的纳米级PMMA接触电荷。SnO2/Ag层由于靠近PMMA/ITO表面,导致电子场发射,轻敲SnO2/Ag层可能导致电子云重叠。与半导体/绝缘体界面类似,SnO2的费米能级在电子输运中起着至关重要的作用。系统效率被描述为传统键盘中的触摸检测器,它可以产生自己的能量,通过对其工作状态的分析可以部分地揭示到4V。
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