Preparation and physical properties of biodegradable polybutylene succinate/polybutylene adipate-co-terephthalate blend monofilament by melt spinning

Seong-wook Park, S. Kim, H. Choi, H. Cho
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引用次数: 25

Abstract

In order to improve the breaking strength and elongation of Polybutylene succinate (PBS) monofilament, themonofilament was produced by blending PBS and Polybutlyne adipate-co-terephthalate (PBAT). ThePBS/PBAT blend monofilament was prepared by the melt spinning system, and the weight ratios of thecompositions of PBS/PBAT was 100/0, 95/5, 90/10 and 85/15, respectively. The breaking strength,elongation, softness and crystallization of PBS/PBAT blend monofilament were analyzed by using atensionmeter, softness measurement, X-ray diffractometer in the both dry and wet conditions. ThePBS/PBAT blend monofilaments were spun in the take-up velocity of 1.19m/sec under the drawing ratio of6.8:1 condition. The production volumes of PBS/PBAT blend monofilaments showed 20% less than that ofNylon. The breaking strength of PBS/PBAT blend monofilaments were decreased as PBAT contentsincreased, while elongation and softness were increased. In case of PBAT content were over 5%, thebreaking strength, elongation and softness of PBS/PBAT blend monofilaments were not shown to increasein spite of increasing in PBAT contents. Based on these results, it was possible to make the monofilamentswith the maximized physical properties when the PBAT contents at 5%.Keywords: Biodegradation, Polybutylene succinate, Monofilament, Physical properties
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熔融纺丝法制备可生物降解聚丁二酸丁二酯/聚己二酸丁二酯共混单丝及其物理性能
为了提高聚丁二酸丁二酯(PBS)单丝的断裂强度和伸长率,将PBS与己二酸聚丁二酯(PBAT)共混制备了聚丁二酸丁二酯单丝。采用熔融纺丝体系制备了PBS/PBAT共混单丝,其配比分别为100/0、95/5、90/10和85/15。采用张力仪、柔软度仪、x射线衍射仪对PBS/PBAT共混单丝在干湿两种条件下的断裂强度、伸长率、柔软度和结晶性进行了分析。在拉伸比为6.8:1的条件下,以1.19m/s的卷绕速度纺制了pbs /PBAT共混单丝。PBS/PBAT共混单丝的产量比尼龙少20%。随着PBAT含量的增加,PBS/PBAT共混单丝的断裂强度降低,伸长率和柔软度增加。当PBAT含量大于5%时,PBS/PBAT共混单丝的断裂强度、伸长率和柔软度不随PBAT含量的增加而增加。结果表明,当PBAT含量为5%时,可以制备出具有最大物理性能的单丝。关键词:生物降解,聚琥珀酸丁二烯,单丝,物理性能
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