Study of Various Electrospinning Parameters on Nanofibers Morphology for Flexible Devices

K. Khanum, Gowda K. Akshay, S. Biswas, Praveen C Ramamurthy
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Abstract

Flexible and lightweight polymer layers with surface topographies are sought-after as substrates to fabricate wearable sensors, displays and photovoltaic devices. This study demonstrates the nanofibers of various topographies through electrospinning. Initially, three important electrospinning parameters are selected, such as applied voltage, flow rate and needle diameter and the variation in nanofibers diameter with respect to these parameters are established. Further, based on established parameters, the effect of needle geometry, solvent, polymer and polymer blend are evaluated. The obtained nanofibers mats are flexible, free-standing and are mostly made up of inexpensive and commercially-available polymers such as polyvinyl alcohol (PVA), poly (methyl methacrylate) PMMA and poly (ethylene oxide) PEO. The topographies obtained are round, flat, conjoined, wrinkled, porous striated and wrinkled with fibers diameter varying from 225 to 1300 nm. Thus, in this study, a single-step process is demonstrated for the generation of nanofibers mats with various topographies.
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不同静电纺丝参数对柔性器件纳米纤维形态的影响研究
具有表面形貌的柔性轻质聚合物层作为制造可穿戴传感器、显示器和光伏设备的基板受到追捧。本研究通过静电纺丝的方法,展示了不同形貌的纳米纤维。首先,选取了三个重要的静电纺丝参数,如施加电压、流量和针径,建立了纳米纤维直径随这些参数的变化规律。在此基础上,对针形、溶剂、聚合物和聚合物共混物的影响进行了评价。所获得的纳米纤维垫是柔性的,独立的,主要由廉价和商业上可用的聚合物组成,如聚乙烯醇(PVA),聚(甲基丙烯酸甲酯)PMMA和聚(环氧乙烷)PEO。得到的形貌为圆形、扁平、连体、皱褶、多孔条纹和皱褶,纤维直径从225到1300 nm不等。因此,在本研究中,证明了一种单步工艺可以生成具有不同地形的纳米纤维垫。
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