Generation of furanic compounds in transformer oil under accelerated thermal and electrical stress

P. Verma, M. Roy, R. Tiwari, S. Chandra
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引用次数: 25

Abstract

High voltage transformers use Kraft paper to insulate the electrical windings present in the core, which is then subsequently immersed in oil. In service, the temperature of the windings will increase to typically 80degC. If the transformer is loaded to beyond its design ratings, the temperature can exceed 100degC causing the cellulose chains in the paper to cleave at an accelerated rate, resulting in the degradation of mechanical strength and performance of the insulation. If unchecked, this can lead to catastrophic failure of the transformer and accompanying disruption to electricity supply and large economic losses to the operating utility. Furfuraldehyde (FFA) is a chemical by-product, which is released into the oil by the thermal degradation of the paper winding. The concentration of FFA within the oil has been directly related to the condition of the paper insulation. Therefore, efforts are made to find the degradation of paper by evaluating the furfural compounds under accelerated thermal and electrical stress and results are correlated with degree of polymerization and tensile strength of paper. The samples are tested at 120degC, 140degC and 160degC and at electric stress 2.5 kV for 360, 720, 1080 and 1440 hours. It was observed that the Furan analysis was the best method for assessing the condition of paper insulation, as this method required the transformer oil to be sampled out and not the paper from the transformer during on-line operation of the transformer
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加速热应力和电应力作用下变压器油中呋喃化合物的生成
高压变压器使用牛皮纸将铁芯中的电气绕组绝缘,然后将其浸入油中。在使用中,绕组的温度通常会增加到80摄氏度。如果变压器负荷超过其设计额定,温度可能超过100℃,导致纸张中的纤维素链加速断裂,导致绝缘材料的机械强度和性能下降。如果不加以控制,这可能导致变压器的灾难性故障,并伴随电力供应中断和运营公用事业的巨大经济损失。糠醛(FFA)是一种化学副产物,通过纸张缠绕的热降解释放到油中。油中游离脂肪酸的浓度直接关系到纸的绝缘状况。因此,我们试图通过评价糠醛化合物在加速热应力和电应力下对纸张的降解,并将结果与纸张的聚合度和抗拉强度相关联。样品分别在120℃、140℃、160℃和2.5 kV电应力下进行360、720、1080、1440小时的测试。结果表明,呋喃分析是评估纸绝缘状况的最佳方法,因为该方法需要在变压器在线运行时抽取变压器油,而不是从变压器中抽取纸
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