Design and Optical Studies for Nanostructure Intermediate Reflector based Perovskite Silicon Tandem solar cell

B. Kumar, N. Gupta
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Abstract

In Perovskite-silicon tandem (PST) solar cells, the final current density of cell is decided by the smallest current generated by the perovskite sub cells, as the two cells are in series. Commonly, processing defects occur in thick perovskite layers, which limits the thickness of top perovskite layer. Due to the limited thickness of top perovskite cell (PerC), the cell cannot absorb the photons as it could be, limits the final current density of PST cell. To increase the top cell current, this paper presents the design and discusses the role of nanostructured intermediate reflector (IR). The bottom C-Si cell is optimized to match with the top cell current density. The numerical analysis of the proposed design shows that there is only slight increase in the top cell current density with the presented nanostructured IR. The theoretical analysis is done to understand, the reason behind getting only a slight increase in top cell absorption with patterned IR using effective medium theory. It has been observed that the low index contrast of the materials involved in the IR design are the main reason for low absorption enhancement. The methods that can be used as an alternate to the proposed design to further improve the top cell current density are also discussed.
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纳米结构钙钛矿硅串联太阳能电池的设计与光学研究
在钙钛矿-硅串联(PST)太阳能电池中,由于钙钛矿亚电池是串联的,因此电池的最终电流密度由钙钛矿亚电池产生的最小电流决定。通常,加工缺陷发生在较厚的钙钛矿层中,这限制了顶层钙钛矿层的厚度。由于顶部钙钛矿电池(PerC)的厚度有限,电池不能充分吸收光子,限制了PST电池的最终电流密度。为了提高顶电池电流,本文提出了纳米结构中间反射器(IR)的设计方案,并对其作用进行了讨论。底部的C-Si电池被优化以匹配顶部电池的电流密度。对所提出的设计进行的数值分析表明,所提出的纳米结构红外只略微增加了顶部电池的电流密度。利用有效介质理论对图像化红外的顶板吸收率只有轻微提高的原因进行了理论分析。已经观察到,红外设计中涉及的材料的低折射率对比度是低吸收增强的主要原因。本文还讨论了可用于替代所提出的设计以进一步提高顶电池电流密度的方法。
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