Ultrafast transient absorption investigation on the photochemical reaction mechanisms of selected aromatic carbonyl compounds

Ma Jianni, G. Yan, Phillips David Lee
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Abstract

In our recent years' study, femtosecond time-resolved transient absorption spectroscopy experiments and density functional theory computations are done for the mechanistic investigation of selected aromatic carbonyl compounds, especially for some photochemical reactions in water containing solutions. We will reported some of our investigated systems, like the photoredox reaction mechanism study on benzophenone and anthraquinone compounds, 1 2 3 4 5 6 7 8 9 the photodeprotection reaction mechanism on selected photoliable protecting groups 101112 and the photoinduced generation of quinone methides species. 1314
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选定芳香羰基化合物光化学反应机理的超快瞬态吸收研究
本文采用飞秒时间分辨瞬态吸收光谱实验和密度泛函理论计算,对选定的芳香羰基化合物进行了机理研究,特别是对某些含水溶液中的光化学反应进行了研究。我们将报道我们研究的一些体系,如二苯甲酮和蒽醌类化合物的光氧化还原反应机理研究,12 3 4 5 6 7 8 9选定的光敏保护基团101112的光去保护反应机理和光诱导产生的醌类化合物。1314
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