Application of Conductometric Capillary Electrophoresis Microchip in Detect Organic and Inorganic Ions

Y. Chu, Ming-Tai Lu, Hsien-Chang Chang
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Abstract

Conductivity detection can be considered electrochemical technique as well but has the ability to detect any analyte irrespective of whether it contains an or not. The authors used MEMS to fabricate the microelectrode. The microchannel was made by PDMS and modified by O2 plasma. In this study the authors detected organic components such as catechol, dopamine, histamine and vitamin C, and inorganic ions like K+, Li+ and Ca2+. In 30 sec electrokinetic injection time for individual sample detection was performed using a field strength (E) of 440 V/cm, and E = 230 V/cm for separation electrophoresis. Each sample can be detected less than 90 sec excluding catechol.
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毛细管电导电泳芯片在有机和无机离子检测中的应用
电导率检测也可以被认为是电化学技术,但它具有检测任何分析物的能力,而不管它是否含有苯胺。采用微机电系统(MEMS)制备微电极。采用PDMS制备微通道,O2等离子体修饰微通道。在这项研究中,作者检测了有机成分,如儿茶酚、多巴胺、组胺和维生素C,以及无机离子,如K+、Li+和Ca2+。在30秒的电动注射时间内对单个样品进行检测,使用电场强度(E)为440 V/cm, E = 230 V/cm进行分离电泳。除儿茶酚外,每个样品可在90秒内检测到。
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