Study on the High Temperature Melting Treatment of Nuclear Waste Glass Fiber

Chunyu Liu, Yan Wen
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Abstract

In abroad, the treatment method adopted for the wastes above is mechanical compression and storage [1–2]. In domestic, the wastes management methods could be summarized as follows according to the surface dose of the waste substance: (1) Waste filter cores with a surface dose rate greater than 2 mSv/h are fixed in a 400L steel drum with cement in the cement solidified line of nuclear auxiliary plant (NX), and one waste filter core is installed in a 400L drum [3–5]. After reconditioning, the waste volume is 0.4m3; By storing decay, the surface dose rate of some of the high dose rate level waste filter cores decreased to below 2 mSv/h, and then they were dried, super-compacted and cemented, which greatly reduced the amount of waste generated. (2) The waste filter elements with the surface dose rate below 2 mSv/h are packed into 200L steel drums and sent to the waste treatment auxiliary workshop (QS) for drying, super compaction and cement fixation. About 3∼4 waste filter elements are packed into a 400L drum. After preparation, the average waste volume of each filter core is 0.1m3. However, the treatment time of these methods is very long, the volume of waste after treatment is still relatively large, and the storage and isolation time is long. To sum up, this paper innovatively adopted high-temperature melting method to conduct glass solidification treatment on the simulated contaminated glass fiber, and by this method it forms a stable glass body with stable chemical properties. Moreover, it reduces the waste volume and directly forms a solidified body which is more convenient for treatment and disposal.
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高温熔融处理核废料玻璃纤维的研究
国外对上述废弃物的处理方法为机械压缩储存[1-2]。在国内,根据废物表面剂量,废物管理方法可归纳为:(1)在核辅厂(NX)水泥固化线,将表面剂量率大于2 mSv/h的废物滤芯与水泥一起固定在400L钢筒中,并将一个废物滤芯安装在400L钢筒中[3-5]。改造后废液体积为0.4m3;通过贮存衰变,部分高剂量率级废滤芯的表面剂量率降至2 mSv/h以下,然后进行干燥、超压实和胶结处理,大大减少了废物的生成量。(2)表面剂量率低于2msv /h的废滤芯装入200L钢桶,送至废物处理辅助车间(QS)烘干、超压实、水泥固定。约3 ~ 4个废滤芯装入400L的桶中。制备后,每个滤芯的平均废物体积为0.1m3。但是,这些方法的处理时间都很长,处理后的废弃物体积仍然比较大,储存和隔离时间也比较长。综上所述,本文创新性地采用高温熔融法对模拟污染的玻璃纤维进行玻璃固化处理,形成化学性质稳定的稳定玻璃体。而且减少了废物体积,直接形成固化体,更便于处理处置。
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