Diketopyrrolopyrrole based polymers for n-type organic electrochemical transistors

J. J. Samuel, A. A. Mohapatra, Puttaraju Boregowda, S. Patil, Nagaphani B. Aetukuri
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Abstract

Organic electrochemical transistors (OECTs) find applications in biosensing and bioelectronics. Availability of p- and n-type OECT materials with balanced performance is key to the development of OECT-based circuits for performing multiplexing and signal processing functions in bioelectronic devices. However, the performance of n-type OECT materials lags behind the best p-type materials by several orders of magnitude and there is a clear need for the development of new n-type OECT materials. Here, we report a diketopyrrolopyrrole (DPP) based polymer as a potential candidate material for n-type OECTs. We fabricated DPP-based OECTs and report stable operation of the devices in an aqueous electrolyte
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n型有机电化学晶体管用双酮吡咯基聚合物
有机电化学晶体管(OECTs)在生物传感和生物电子学中得到了广泛的应用。具有平衡性能的p型和n型OECT材料的可用性是开发基于OECT的电路以在生物电子器件中执行多路复用和信号处理功能的关键。然而,n型OECT材料的性能落后于最好的p型材料几个数量级,显然需要开发新的n型OECT材料。在这里,我们报道了一种基于二酮吡咯(DPP)的聚合物作为n型oect的潜在候选材料。我们制作了基于dpp的OECTs,并报告了该器件在水电解质中的稳定运行
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