Study on isotope mass difference (16O, 18O) effect on CO2 laser oscillation spectra

Yasuyuki Saito
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Abstract

It is difficult to explain continuity between12C16O2−12C16O2−12C18O2 laser oscillation spectra due to only oxygen isotope–mass–difference (16O, 18O) effect on rotation energy level of fine structure for 00°1 to 10°0 of transition of CO2 molecules. In order to explain fine structure interval of CO2 laser oscillation spectra, it is necessary to consider CO2 molecule shape of smaller O=C bond length (this means smaller rotation inertia moment of a CO2 molecule) through nuclear characteristics (for example, gravity center, shape, spin) in a CO2 molecule.
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同位素质量差(16O, 18O)对CO2激光振荡光谱影响的研究
12C16O2 - 12C16O2 - 12C18O2激光振荡光谱的连续性很难解释,因为只有氧同位素-质量差(16O, 18O)对CO2分子跃迁00°1 ~ 10°0精细结构的旋转能级有影响。为了解释CO2激光振荡光谱的精细结构区间,需要通过CO2分子中的核特征(如重心、形状、自旋)考虑O=C键长度较小的CO2分子形状(即CO2分子的旋转惯量较小)。
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