The Partial Discharge Characteristics of PI Film Modified by Nano-Al₂O₃ in Liquid Nitrogen

Daosheng Liu, Liang Zhang, Guangkang Wang
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Abstract

The polyimide (PI) film is used as the internal insulation system in the high-temperature superconducting transformer due to its excellent mechanical and electrical performance. Many researchers had found that nanoparticle mixing can improve the polymer’s insulation properties. The partial discharge(PD) will induce the deterioration and even breakdown of the insulating materials. In the paper, the PI films modified by nano-A12 O3 were prepared in situ polymerization. The particle size of Al2 O3 nanoparticle used in this research is 10 nm, and the mass fraction is 1wt%, 3wt%, 5wt% and 7wt%, respectively. The volume resistivity, surface resistivity and partial discharge initial voltage (PDIV) are measured in liquid nitrogen(LN). The experimental results indicate that adding of 3wt% nanoparticle is the optimum ratio to suppress the PD in the PI films.
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纳米al₂O₃改性PI膜在液氮中的局部放电特性
聚酰亚胺(PI)薄膜因其优异的机械性能和电气性能而被用作高温超导变压器的内部绝缘系统。许多研究人员发现,纳米颗粒的混合可以改善聚合物的绝缘性能。局部放电会引起绝缘材料的劣化甚至击穿。本文采用原位聚合法制备了纳米a12o3改性的PI薄膜。本研究使用的al2o3纳米颗粒粒径为10 nm,质量分数分别为1wt%、3wt%、5wt%和7wt%。测量了液氮介质中的体积电阻率、表面电阻率和局部放电初始电压(PDIV)。实验结果表明,在PI膜中加入3wt%的纳米粒子是抑制PD的最佳配比。
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