Modified Polyimide Polymers for Electro-Optic Applications

P. Prêtre, P. Kaatz, A. Bohren, P. Günter, B. Zysset, M. Ahlheim, F. Lehr
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Abstract

Novel amorphous nonlinear optical (NLO) polymers with modified polyimide backbones and functionalized azo chromophores have been synthesized for applications as electro-optic materials. The most attractive aspects of these polymers are the ease of modification of the NLO side-chain chromophores and the high thermal stability provided by glass transition temperatures in excess of 140 °C. The dispersion of the linear and nonlinear optical properties of these polymers has been determined. The time-temperature behaviour of the chromophore relaxation has been modeled to obtain estimates of the lifetimes of electro-optic devices using these polymers.
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电光应用的改性聚酰亚胺聚合物
合成了具有改性聚酰亚胺骨架和功能化偶氮发色团的新型非晶态非线性光学聚合物(NLO),可作为电光材料。这些聚合物最吸引人的方面是易于修饰NLO侧链发色团,以及在超过140°C的玻璃化转变温度下提供的高热稳定性。测定了这些聚合物的线性和非线性光学性质的色散。对生色团弛豫的时间-温度行为进行了建模,以获得使用这些聚合物的电光器件寿命的估计。
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