Synthesis and Characterization of Rare Earth (Ce) Substituted Magnesium Ferrite MgCe0.1Fe1.9O4 and Banana Peel BPMgCe0.1Fe1.9O4

Atiq Ur Rehman, Mukhtar Ahmad
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Abstract

In this study, a composite of cerium doped magnesium ferrite (MgCexFe2-xO4 , x= 0.1) and banana peel powder was prepared by hydrothermal method.  Crystal structure and phase identification, chemical bonding, and magnetic properties were characterized by X-ray diffraction (XRD), Fourier transform infrared (FTIR) and vibrating sample magnetometery (VSM), respectively. XRD results reveal that the prepared ferrite exhibits single phase face centered cubic (fcc) structure having no impurity in the sample. Addition of banana peel powder has no effect on the crystal structure. The values of structural parameters greatly match with the earlier reported values for the same structure. FTIR results clearly indicate that the prepared ferrite is spinel and have well defined vibrational and stretching peaks due to different molecules present in the compound. Coercivity values for both ferrite and composite materials are found to be a few hundred Oersted which confirm the soft magnetic nature of this ferrite. The observed parameters show that the prepared composite may find technological application for microwave absorption and multi-layer chip inductors.
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稀土(Ce)取代铁氧体镁mgce0.1 fe1.90 o4和香蕉皮bpmgce0.1 fe1.90 o4的合成与表征
本研究采用水热法制备了掺铈铁酸镁(mgceexfe2 - xo4, x= 0.1)与香蕉皮粉的复合材料。采用x射线衍射(XRD)、傅里叶变换红外(FTIR)和振动样品磁强计(VSM)分别对晶体结构和物相识别、化学键和磁性能进行了表征。XRD结果表明,制备的铁氧体呈单相面心立方(fcc)结构,样品中没有杂质。香蕉皮粉的加入对晶体结构没有影响。结构参数的值与先前报道的相同结构的值有很大的匹配。FTIR结果清楚地表明制备的铁氧体为尖晶石,并且由于化合物中存在不同的分子而具有明确的振动和拉伸峰。铁氧体和复合材料的矫顽力值均为几百欧氏体,证实了铁氧体的软磁性质。实验结果表明,所制备的复合材料可用于微波吸收和多层片式电感。
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