Development and characterization of new XLPE compounds for high performance cables in the automotive industry

J. Rompante, A. Vieira, F. Amaral, Pinedo Aa, J. Goncalves, E. Oliveira, Conceição Ds
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Abstract

The materials employed in the electrical insulation of cables/wires used in the automotive industry are exposed to several external factors that may affect the overall performance of the system. These factors include mechanical vibrations, high temperature, humidity, wind and rain. In order to have a stable and trustworthy solution, these materials need to follow specific criteria in what regards their abrasion, thermal and chemical resistance, flame retardancy, and mechanical properties. In this work, new crosslinked polyethylene (XLPE) compounds were developed by means of compound extrusion, using peroxide crosslinking, and also different polymeric matrices. Ultimately, blends of ethylene-vinyl-acetate (EVA) and low density polyethylene (LDPE) with alumina trihydrate (ATH) and magnesium hydroxide (MH), exhibited a significant increase in both the oxidation-induction time – higher than 95 min (OIT), and abrasion resistance (sandpaper abrasion) – approximately 38.1 g, while maintaining a low density profile and fair mechanical properties, when compared with the selected standard material, based on a ATH-additivated EVA material. These findings show that such material can be considered as a promising and suitable candidate for high performance cables.
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用于汽车行业高性能电缆的新型XLPE化合物的开发和表征
汽车工业中使用的电缆/电线的电气绝缘材料暴露于几个可能影响系统整体性能的外部因素中。这些因素包括机械振动、高温、湿度、风和雨。为了获得稳定可靠的解决方案,这些材料需要在耐磨性、耐热性和耐化学性、阻燃性和机械性能方面遵循特定的标准。本文通过复合挤出、过氧化物交联和不同聚合物基体制备了新型交联聚乙烯(XLPE)化合物。最终,乙烯-乙烯-乙酸酯(EVA)和低密度聚乙烯(LDPE)与三水合氧化铝(ATH)和氢氧化镁(MH)的共混物在氧化诱导时间(超过95分钟)和耐磨性(砂纸磨损)(约38.1 g)方面都有显著增加,同时保持了低密度轮廓和良好的机械性能,与选择的标准材料相比,基于ATH添加的EVA材料。这些发现表明,这种材料可以被认为是一种有前途的和合适的高性能电缆候选材料。
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