{"title":"Phase Transitions","authors":"R. Swendsen","doi":"10.1093/oso/9780198853237.003.0017","DOIUrl":null,"url":null,"abstract":"Phase transitions are introduced using the van der Waals gas as an example. The equations of state are derived from the Helmholtz free energy of the ideal gas. The behavior of this model is analyzed, and an instability leads to a liquid-gas phase transition. The Maxwell construction for the pressure at which a phase transition occurs is derived. The effect of phase transition on the Gibbs free energy and Helmholtz free energy is shown. Latent heat is defined, and the Clausius–Clapeyron equation is derived. Gibbs' phase rule is derived and illustrated.","PeriodicalId":102491,"journal":{"name":"An Introduction to Statistical Mechanics and Thermodynamics","volume":"41 1","pages":"0"},"PeriodicalIF":0.0000,"publicationDate":"2019-12-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"An Introduction to Statistical Mechanics and Thermodynamics","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1093/oso/9780198853237.003.0017","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 0
Abstract
Phase transitions are introduced using the van der Waals gas as an example. The equations of state are derived from the Helmholtz free energy of the ideal gas. The behavior of this model is analyzed, and an instability leads to a liquid-gas phase transition. The Maxwell construction for the pressure at which a phase transition occurs is derived. The effect of phase transition on the Gibbs free energy and Helmholtz free energy is shown. Latent heat is defined, and the Clausius–Clapeyron equation is derived. Gibbs' phase rule is derived and illustrated.
京公网安备 11010802042870号
京ICP备2023020795号-1
分享
求助内容：
应助结果提醒方式：
扫码关注我们
