Photo-catalytic degradation of Toluidine Blue Dye in Aqueous Medium Under Fluorescent Light

Haydar A. Mohammad Salim, Shinwar Ahmed Idrees, R. A. Rashid, Abraheem Ali Mohammed, S. Simo, Idrees Salim Khalo
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引用次数: 8

Abstract

The photo-catalytic degradation of Toluidine Blue dye (TB) in aqueous suspension solution has been studied utilizing fluorescence light and using Zinc oxide (ZnO) as a semiconductor at variety working factors. The studied parameters were concentration of dye, semiconductor dose and the influence of pH. The result shows that expanding of ZnO dose from 20 to 60 mg/L increases the removal rate of TB dye. On the other hand, the adding of concentration from 5 to 15 mg/L show negative effect on the rate of photo-degradation. It has been denoted that the percentage of dye degradation come to the peak value at high acidic medium. 11 % of TB dye was adsorbed, in dark condition, by ZnO. In addition, the kinetics of degradation has been examined and the degradation was found to take after pseudo-first order kinetic model.
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荧光光催化降解水中苯胺蓝染料的研究
以氧化锌(ZnO)为半导体材料,在不同的工作因子下,利用荧光光催化降解水中的甲苯胺蓝染料(TB)。研究了染料浓度、半导体用量和ph的影响。结果表明,当ZnO用量从20 mg/L增加到60 mg/L时,对TB染料的去除率提高。另一方面,添加浓度在5 ~ 15 mg/L范围内对光降解速率呈负向影响。结果表明,在高酸性介质中,染料降解率达到峰值。在黑暗条件下,11%的TB染料被ZnO吸附。此外,对降解动力学进行了研究,发现降解符合准一级动力学模型。
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